We study a reaction-diffusion system which models the pre-mixed isothermal autocatalytic chemical reaction of order m (m > 1) between two species, reactant A and an auto-catalyst B, + B --> (m+1) linear decay -->C, where C is inert product. The special case = 2 much studied Gray-Scott model, but without feeding. prove existence multiple traveling waves have distinctive number local max...

Kinetics of enzymic oxidation of indoleacetic acid (ISA) are interpreted as indicating that the reaction has an autocatalytic, cyclical mechanism invol\-ing unst,ablc intermcdiatcs whose formation and disappearance are important in determining the over-all reaction rate. The kinetics do not supporl the idea that IAA oxidation occurs mainly by reaction with Mnt3, nor that the reaction is an elec...

The influence of temperature and relative air humidity on the stability of the novel derivative of daunorubicin: [(N-morpholine)metylene]daunorubicin hydrochloride was investigated. The process of degradation was studied by using high-performance liquid chromatography with ultraviolet (UV) detection. In dry air, the degradation of [(N-morpholine)metylene]daunorubicin hydrochloride was a first-o...

The synthesis of enantiopure molecules from achiral precursors without the need for pre-existing chirality is a major challenge associated with the origin of life. We here show that an enantiopure product can be obtained from achiral starting materials in a single organic reaction. An essential characteristic of this reaction is that the chiral product precipitates from the solution, introducin...

The influence of temperature and relative air humidity on the stability of cefaclor monohydrate in crystalline form and in its pharmaceutical preparations (oral suspension and slow release tablets) was investigated. The process of degradation was studied by using high-performance liquid chromatography with ultraviolet (UV) detection, as described in the monograph of cefaclor in European Pharmac...

A self-reproducing cycle has the fundamental organization, A + X −→ 2A, and is autocatalytic, i.e. the products catalyze the formation of the products. The rate of increase of A is proportional to A, i.e. exponential. Asexual living entities often grow exponentially when resources are abundant, and decay exponentially when resources are scarce, according to autocatalytic kinetics. If two previo...

The autocatalytic processing of procathepsin L was investigated in vitro using purified recombinant proenzyme expressed in Pichia pastoris. Pure intermolecular processing was studied by incubating the mutant procathepsin L (C25S), which cannot autoactivate with a small amount of mature active cathepsin L. The results clearly establish that, contrary to recent reports, intermolecular processing ...

The initial rate of formation of chlorine dioxide in the chlorite-tetrathionate reaction changes in an unusual fashion. The formal kinetic order of both reactants varies over a very wide range. Moreover, chlorite ion behaves not just as a simple reactant, but also as a self-inhibitor. A five-step scheme, derived from an eight-step mechanism, is proposed in which the autocatalytic formation of H...

Spatiotemporal pattern formation in the autocatalytic chlorite–tetrathionate reaction is studied experimentally in porous media where heterogeneities are introduced as glass beads packed in a monolayer. From initially vertical planar chemical fronts in a vertical slab, asymmetric convective structures with stable geometry evolve which propagate horizontally with constant speed. The single conve...