The ability of a complex mixture of organic compounds found in secondary organic aerosol (SOA) to act as a photosensitizer in the oxidation of volatile organic compounds (VOCs) was investigated. Different types of SOAs were produced in a smog chamber by oxidation of various biogenic and anthropogenic VOCs. The SOA particles were collected from the chamber onto an inert substrate, and the result...

In situ microscopy provides dynamic information about nucleation, growth and coalescence of islands in real time. We utilised in situ ultra-high vacuum transmission electron microscopy to gain fundamental insights into the oxidation of Cu films. A semiquantitative model, where oxygen surface diffusion is the dominant mechanism for transport, nucleation and growth of the copper oxide, describes ...

In the present work, nano scaled zero valent irons (nZVI) were synthesized in ethanol medium by the method of ferric iron reduction using sodium borohydride as a reducing agent under atmospheric conditions. The obtained iron nanoparticles are mainly in zero valent oxidation state and remain without significant oxidation for weeks. A systematic characterization of nZVI was performed using UV, XR...

Dielectric Barrier Discharges (DBD) operated at atmospheric pressure and working at reduced temperatures (T < 115 degrees C) and a copper-manganese oxide catalyst are combined for the direct decomposition and the steam reforming of methanol (SRM) for hydrogen production and for the preferential oxidation of CO (CO-PROX).

In the stratosphere, the ozone (O3) plays a role of natural and beneficial screen in relation to the harmful effects of ultraviolet (UV) for the organic matter (= good ozone). In the troposphere, O3 is a pollutant that is produced during the atmospheric photo-oxidation of ozone precursors: Volatile Organic Compounds (VOCs) and nitrogen oxides (NOx) mainly emitted by anthropogenic activities (= ...

Parametric sensitivity and uncertainty analysis of dimethylsulfide oxidation in the remote marine boundary layer D. D. Lucas * and R. G. Prinn Department of Earth, Atmospheric, and Planetary Sciences, MIT, Cambridge, MA 02139, USA Present address: Frontier Research Center for Global Change, Yokohama, Japan Received: 18 August 2004 – Accepted: 23 September 2004 – Published: 7 October 2004 Corres...

Transition metal-free oxidation with air at room temperature has been achieved by simply using ascorbate (vitamin C) and catalytic amounts of menadione (vitamin K3). A combination of the mentioned vitamins transforms atmospheric oxygen into hydrogen peroxide, which is able to oxidize arylboronic acids and other chemical moieties.

Recent experimental findings indicate that HSO5 radicals may play a key role in the nucleation of atmospheric SO2 oxidation products. HSO5 radicals are metastable intermediates formed in the SO2 oxidation process, and their stability and lifetime are, at present, highly uncertain. Previous high-level computational studies have predicted rather low stabilities for HSO5 with respect to dissociati...

Abstract. The photo-oxidation of myrcene, a monoterpene species emitted by plants, was investigated at atmospheric conditions in the outdoor simulation chamber SAPHIR (Simulation Atmospheric PHotochemistry In Large Reaction Chamber). chemical structure myrcene consists one moiety that is conjugated ? system (similar to isoprene) and another triple-substituted olefinic unit 2-methyl-2-butene). H...

High-resolution geochemical analyses of organic-rich shale and carbonate through the 2500 million-year-old Mount McRae Shale in the Hamersley Basin of northwestern Australia record changes in both the oxidation state of the surface ocean and the atmospheric composition. The Mount McRae record of sulfur isotopes captures the widespread and possibly permanent activation of the oxidative sulfur cy...