نتایج جستجو برای: asymmetric synthesis
تعداد نتایج: 470048 فیلتر نتایج به سال:
Studies on Asymmetric Synthesis. V. Asymmetric Reductions of (-)-Menthyl Aliphatic α-Ketocarboxylate
A time-varying, analysis/synthesis auditory filterbank has been developed using a new implementation of the "gammachirp", which has been shown to be an excellent function for the asymmetric, level-dependent auditory filter. The gammachirp filter is shown to be implemented through a combination of a gammatone filter and an IIR asymmetric compensation filter; which largely reduces the computation...
Over the years, considerable effort has been made toward the development of new synthetic routes to monosaccharides [1]. This interest came primarily from the medicinal chemistry community, as these new routes often provided access to unnatural sugars, which could be of use in structure–activity relationship (SAR) studies. In addition, the synthesis of monosaccharides, and in particular hexoses...
A new approach to the anticancer drug Velcade was developed by performing asymmetric borylation of an imine anchored with a chiral N-phosphinyl auxiliary. Throughout the 7-step synthesis, especially in the imine's synthesis and in the asymmetric borylation reactions, operations and work-up were conducted in simple and easy ways without any column chromatographic purification, which defines the ...
We present the synthesis of novel asymmetric indolonaphthyridines with enhanced excited state charge-transfer character relative to symmetrical indolonaphthyridine.
in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...
Since their discovery, cyclodextrins have widely been used as green and easily available alternatives to promoters or catalysts of different chemical reactions in water. This review covers the research and application of cyclodextrins and their derivatives in asymmetric and stereospecific syntheses, with their division into three main groups: (1) cyclodextrins promoting asymmetric and stereospe...
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