The influence of pH on the stability of cefpirome sulfate was investigated in the pH range of 0.44 - 13.00. The degradation of cefpirome sulfate as a result of hydrolysis was a pseudo-first-order reaction. General acid-base hydrolysis of cefpirome sulfate was not observed. In the solutions of hydrochloric acid, sodium hydroxide, acetate, borate and phosphate buffer, k(obs) = k(pH) because speci...

A simple two order-paraIneter Ginzburg-Landau theory for binary mixtures of water and amphiphile is introduced. The amphiphile concentration is described by a scalar, the orientational degrees of freedom of the amphiphile by a vector order parameter. Phase diagrams are calculated by minimizing the free energy functional. Several ordered lyotropic phases of lamellar, hexagonal, inverse hexagonal...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

In this study, speciation in aqueous solutions of nitric acid at 25 °C was assessed in two independent ways. First, Raman experiments were carried out and interpreted in terms of free nitrate ions, ion pairs and neutral HNO(3) molecules. In parallel, a model was developed to account for the formation of these two kinds of pairs. It was based on an extension of the binding mean spherical approxi...

Due to the disadvantages of heavy metal removal from aqueous sytems by conventional methods, alternative new methods have been investigated lately. Biosorption is one of these new methods. In this method, metal ions are transported into cell structure, and removal is ensured by several mechanisms that occured between living or non-living microorganisms and metal ions. The metal removal, the use...

The present work reported density, viscosity, speed of sound, electrical conductivity and refractive index data of L-alanine in the aqueous solutions of 1-hexyl-3-methylimidazolium ibuprofenate at T= 298.15 K. Using the measured data, partial molar volume of transfer ( ), partial molar isentropic compressibility of transfer ( ), viscosity B-coefficient of transfer (∆traB), ion association const...

Introduction: There are different methods for removal of cadmium from aqueous solutions. Adsorption based methods are among the bests. One of the most important aspects for adsorption techniques is the availability of an accessible and economical adsorbent. This study aims to investigate cadmium removal from aqueous solutions by walnuts shell waste. Materials and Methods: Walnut Shell (WS) was...

Thermoresponsive behavior of polymers in aqueous solutions has been widely studied and utilized various applications. However, the fundamental understanding on use oil soluble non-aqueous solutions...

In this study, the removal of cadmium and lead ions from aqueous solution by nanocrystalline magnetite was investigated. The nanocrystalline magnetite was synthesized by mechanochemical activation of hematite in a high energy planetary mill in argon atmosphere for 45 hours. The ability of the synthesized nanocrystalline magnetite for removal of Cd(II) and Pb(II) from aqueous solutions was studi...