Nitrogen/sulfur co-doped anatase TiO2 nanocrystals with a high specific surface area and a high percentage of {001} facets were synthesized by a solvent-thermal process followed by the calcination with thiourea at an optimum heat treatment temperature. Under current experimental conditions, the optimum heat treatment temperature was found at 300°C, which successfully introduced nitrogen and sul...

We report the hydrothermal synthesis of graphene (GNP)-TiO2 nanoparticle (NP) hybrids using COOH and NH2 functionalized GNP as a shape controller. Anatase was the only TiO2 crystalline phase nucleated on the functionalized GNP, whereas traces of rutile were detected on unfunctionalized GNP. X-Ray Photoelectron spectroscopy (XPS) showed C-Ti bonds on all hybrids, thus confirming heterogeneous nu...

Anatase TiO2 tree-like nanoarrays were prepared on various metal wires (Ti, W, Ni, etc.) through one-step facile hydrothermal reaction. The anatase TiO2 tree-like nanoarrays consist of long TiO2 nanowire trunks with direct charge transport channels, and a large number of short TiO2 nanorod branches with large surface areas. Fiber dye-sensitized solar cells (FDSSCs) based on the anatase TiO2 tre...

Here we describe the development of a new mesocrytalline anatase-based photocatalyst with an activity nearly double that commercial Evonik Aeroxide® TiO2 P25 catalyst. An extensive characterization this catalytic material XRD, TEM, SAED, EELS, SEM, RAMAN and XPS shows its is promoted by hybrid structure comprising mesocrystalline anatase K2Ti6O13 whiskers formed within mesocrystals. This unexpe...

We report a robust, low-cost method to attach transition metal ions directly to the surface of anatase TiO2 rod-shaped nanocrystals with preservation of the host nanocrystal morphology and phase. The procedure has been optimized to achieve quantitative control of metal ion loading on the surface of the nanorods. The metal ion can be attached to the nanocrystal surface up to fullmonolayer covera...

Ultrafine titanium dioxide (TiO(2)) particles have been shown to exhibit strong cytotoxicity when exposed to UVA radiation, but are regarded as a biocompatible material in the absence of photoactivation. In contrast to this concept, the present results indicate that anatase-sized (10 and 20 nm) TiO(2) particles in the absence of photoactivation induced oxidative DNA damage, lipid peroxidation, ...

Polystyrene (PS) opal and titania (TiO2) inverse opal films were fabricated by the self-assembly colloidal crystal template technique. Based on Bragg’s law, these sensors were used to detect the different concentrations of ethanol solution. The results indicated that TiO2 inverse opal films were advantageous over PS opal film for detecting the ethanol concentration. TiO2 inverse opal films sint...