Perfluorooctanoic acid (PFOA) is a perfluorocarboxylic acid that is difficult to treat by most conventional methods. As a result, it is often removed from solution by adsorption on powdered activated carbon (PAC), followed by incineration of the spent carbon. To provide a new approach for treatment, PFOA was exposed to sulfate radicals (SO4(-•)) produced by thermolysis of persulfate (S2O8(2-)) ...

Removal of natural organic matter (NOMs) from actual water is a major challenge in the context worldwide pollution resources. The removal humic acids system combining biochar adsorption and ultrasonic persulfate oxidation was studied this paper. effects addition, concentration initial pH were investigated. A high rate up to 92.5% achieved for combined biochar/ultrasonic/persulfate system, versu...

In this work, a thermo-responsive and cross-linked fluoropolymer poly(2,2,2-Trifluoroethyl) methacrylate (PTFEMA) was successfully prepared by reversible addition-fragmentation chain transfer (RAFT) mediated aqueous polymerization with a thermo-responsive diblock poly(dimethylacrylamide-b-N-isopropylacrylamide) (PDMA-b-PNIPAM) that performed a dual function as both a nanoreactor and macro-RAFT ...

A novel strategy was developed to synthesize uniform semi-interpenetrating polymer network (semi-IPN) microspheres by premix membrane emulsification combined with one-step polymerization. Synthesized poly(acrylic acid) (PAAc) polymer chains were added prior to the inner water phase, which contained N-isopropylacrylamide (NIPAM) monomer, N,N1-methylene bisacrylamide (MBA) cross-linker, and ammon...

The molecular surface imprinted graft copolymer of chitosan with methyl methacrylate (MIP-CS-g-PMMA) were prepared by free radical polymerization with 5-fluorouracil (5-FU) as the template molecule using initiator of ammonium persulfate as adsorption system. MIPs were characterized by FTIR, X-ray diffraction, thermo-gravimetric analysis, (1)H NMR and SEM. The mechanism of graft copolymerization...

Photo-Initiated Cross-Linked Polyacrylamide Gels for Micro-Device Electrophoresis. (May 2005) Shilpa Agrawal, B.Tech., National Institute of Technology Rourkela Chair of Advisory Committee: Dr. Victor Ugaz Photo-polymerized cross-linked polyacrylamide gels are becoming increasingly important for use in micro-fabricated DNA electrophoresis systems because they allow a concentrated sieving matrix...

Techniques in resin blending are simple and efficient method for improving the properties of polymers, and have been used widely in polymer modification field. However, polymer latex blends such as the combination of latexes, especially the latexes with water-soluble polymers, were rarely reported. Here, we report a core-shell composite latex synthesized using methyl methacrylate (MMA), butyl a...

Polyaniline (PANi)-grafted multiwalled carbon nanotube (MWNT) composite is prepared by a two-step reaction sequence. MWNT is first functionalized with 4-aminobenzoic acid in polyphosphoric acid/phosphorous pentoxide as a ‘‘direct’’ Friedel-Crafts acylation reaction medium. The resultant 4-aminobenzoyl-functionalized MWNT is then treated with aniline using ammonium persulfate/aqueous hydrochlori...

In this work, we synthesized a trypsin-stabilized fluorescent gold nanocluster. It was found that sulfide interacted with the nanocluster, which could result in significant fluorescence quenching. With this quenching effect, a fluorescence sulfide sensor was developed. This sensor responded linearly to sulfide in the range of 50 nM to 8 μM, and was capable of detecting sulfide as low as 5.5 nM....