An overview of the synthesis and characterization of several Pt-Ru or Pt-MoNulcan carbon nanocomposites and one Pt-Rdgraphitic carbon nanofiber nanocomposite is provided. Each binary metal alloy nanocluster composition is accessed through the t h d decomposition of a single-source molecular precursor containing the desired metal stoichiometry. Microwave heating techniques are. used to form a Pt...

Macropolycyclic ligands containing appropriate binding sites and cavities of suitable size and shape, may be designed so as to display molecular recognition in the formation of selective inclusion complexes, cryptates, with metal cations, but also with anions and molecules. Macrobicyclic ligands B form highly stable and selective alkali and alkaline-earth cryptates, displaying a pronounced cryp...

The present authors' systematic studies on growth of novel ceramic layers on Ti metal and its alloys by chemical and heat treatments for inducing bone-bonding bioactivity and some other biological functions are reviewed. Ti metal formed an apatite on its surface in a simulated body fluid, when heat-treated after exposure to strong acid solutions to form rutile surface layer, or to strong alkali...

The shift with increasing concentration of alkali-metal cations of the potentials of both the spike and the hump observed in the cyclic voltammograms of Pt(111) electrodes in sulfuric acid solutions is shown to obey the simple model recently developed by us to explain the effect of non-covalent interactions at the electrical double layer. The results suggest that the model, originally developed...

By treating the electron-ion interaction as a perturbation in the first-principles Hamiltonian, we have calculated the density response functions of a fluid alkali metal to find an interesting charge instability due to anomalous electronic density fluctuations occurring at some finite wavevector Q in a dilute fluid phase above the liquid-gas critical point. Since |Q| is smaller than the diamete...

We consider the stimulated Raman transition between two long-lived states via multiple intermediate states, such as between hyperfine ground states in the alkali-metal atoms. We present a concise treatment of the general, multilevel, off-resonant case, and we show how the lightshift emerges naturally in this approach. We illustrate our results by application to alkali-metal atoms and we make sp...

We analyze second-order M1-M1 and M1-E2 effects on the hyperfine structure HFS of the lowest-energy P states of alkali-metal atoms arising from the coupling of the two J=1 /2,3 /2 fine-structure levels through the hyperfine interaction. We find these effects to be especially sizable in Li, leading to a 9 correction to the most accurate reported experimental value of the A P1/2 HFS constant of L...

Homoatomic polyanions have the basic capability for a bottom-up synthesis of nanostructured materials. Therefore, the chemistry and the structures of polyhedral nine-atom clusters of tetrel elements [E(9)](4-) is highlighted. The nine-atom Zintl ions are available in good quantities for E = Si-Pb as binary alkali metal (A) phases of the composition A(4)E(9) or A(12)E(17). Dissolution or extract...

Intergranular stress corrosion cracking (IGSCC) of Alloy 132 weld metal in light water reactor (LWR) structural components is a great concern. The microstructure of Alloy 132 is dendritic and the grain boundaries that are parallel to the direction of the dendrites growth are known to be most susceptible to cracking. In order to correlate the grain boundary microstructure to IGSCC, and in genera...

Tungsten-alloy has carcinogenic potential as demonstrated by cancer development in rats with intramuscular implanted tungsten-alloy pellets. This suggests a potential involvement of epigenetic events previously implicated as environmental triggers of cancer. Here, we tested metal induced cytotoxicity and epigenetic modifications including H3 acetylation, H3-Ser10 phosphorylation and H3-K4 trime...