A better understanding of protein behavior at solid-liquid interfaces is important to improve our knowledge of various natural and synthetic processes. A few examples where protein adsorption at a solid-liquid interface may play an important role are found in: blood coagulation, artificial kidney failure, biomedical microdevices, self-assembling microelectromechanical systems (MEMS), protein ba...

We describe the first detailed experimental characterization of surface adsorption of an aqueous ion pair and quantify the unusual surface behavior of sodium nitrite, a ubiquitous component of natural waters. The onset of unusually strong adsorption at concentrations as low as ca. 0.1 M resembles the controversial ‘Jones–Ray Effect,’ wherein 13 salts exhibited surface tension minima in the mill...

The goal of this paper is to study a nonlinear model for some chemical reactive flows involving diffusion, adsorption and chemical reactions which take place at the boundary and also in the interior of a periodically perforated material. The effective behavior of such flows is governed by another nonlinear boundary-value problem, which contains extra zero-order terms and captures the effect pro...

We present a synergistic experimental and theoretical study of CO(2)/CH(4) mixture coadsorption in breathing metal-organic framework MIL-53(Al). Mixture adsorption experiments were performed and their results were analyzed by comparing them to predictions made from pure-component adsorption data using the Osmotic Framework Adsorption Solution Theory (OFAST). This analytical model, fully validat...

In this research, Graphene Oxide- Gold nanoparticles (AuNP/GO) were easily fabricated by a redox reaction between GO and chloroauric acid without using any additional reductant and then used to stabilize Pickering emulsions. (AuNP/GO) was investigated by FT-IR spectroscopy. The changes of parameters such as contact time, pH, Amoxicillin initial concentration and temperature were tested and inve...

Removal of Cd 2+ , Pb 2+ , and Ni 2+ from aqueous solutions using cellulosegraft-acrylic acid (C-g-AA) hydrogels was investigated. Various factors affecting the adsorption capacity, such as pH, time, initial ions concentration, and competitive ions, were tested. The results showed that the adsorption of hydrogels was very pH dependent, and maximum adsorption was obtained at a pH of 5.0. The ads...

Naturally occurring contamination of arsenic is of great concern in many Southeast Asian countries especially in Bangladesh. Because of the lack of understanding for the mechanism of As contamination, we have developed two studies through field surveys and laboratory experiments. First topic is focused on the underlying mechanisms controlling large spatial variation of As-contaminated groundwat...

The adsorption behavior of Eu(III) onto silica surface, which was partially coated with Fe(III) or Ti(IV), was investigated to determine Fe(III) or Ti(IV) effects on the surface reaction of lanthanides on mineral surfaces in groundwater. Compared with a parallel uncoated silica, the Fe(III)-coated silica did not enhance the adsorption of Eu(III). However, enhanced adsorption of Eu(III) on the T...

The in uence of the ionic adsorption on the anchoring energy of a nematic liquid crystal sample is investigated. We determine the behavior of the anchoring energy as a function of the thickness of the sample, and as a function of the adsorption energy of ions. We show that the contribution to the anchoring energy, due to ionic adsorption, can be of the same order of magnitude of the bare anchor...

In this study, density functional theory calculations were performed to investigate the influence of oxygen preoccupation on the nitrogen oxide decomposition on rhodium. Besides gauging the coverage dependence of the adsorption energy of NO on the (111) rhodium facet, the influence of the initial oxygen coverage on the kinetics and thermodynamics of the nitrogen oxide decomposition reaction was...