This paper investigates the performance of a high temperature proton exchange membrane PEM fuel cell. Both experimental work and numerical simulation are conducted. The high temperature proton exchange membrane is based on polybenzimidazole PBI doped with phosphoric acid. A single cell with triple serpentine flow channels was operated at steady state at various levels of temperature, pressure, ...

Quaternized polymers as ionomeric binders in the electrode enable operation of alternative fuel cells under high pH conditions or anhydrous to overcome challenges proton exchange membrane cells. Hydrophobicity ionomers derived from fluorine content is beneficial performance, but due synthetic difficulties, not many fluorinated quaternized have been reported with their influence on behavior thes...

The mechanism by which urea and guanidinium destabilize protein structure is controversial. We tested the possibility that these denaturants form hydrogen bonds with peptide groups by measuring their ability to block acid- and base-catalyzed peptide hydrogen exchange. The peptide hydrogen bonding found appears sufficient to explain the thermodynamic denaturing effect of urea. Results for guanid...

Proton exchange membrane fuel cells have been receiving more and more attention these recent years. Maintaining a fuel cell system in correct operating conditions requires good controller. Based on the mathematical model of proton exchange membrane fuel cells described in this paper, the fuzzy logic controllers was designed for the proton exchange membrane fuel cell to make it possible to outpu...

Novel acrylate polymers functionalized with tetrafluorophenyl phosphonic acid groups were prepared by free radical polymerization of ester monomers. Liberation the functions was realized cleavage Me3SiBr and subsequent hydrolysis methanol. The obtained analyzed NMR IR spectroscopy. ion exchange capacity methacrylate polymer determined to 2.8 mmol/g titration 0.1 M NaOH. proton conductivity unde...

The transport of [14C]oxalate (Ox2-) by epithelial brush-border membrane vesicles (BBMV) of lobster (Homarus americanus) hepatopancreas, formed by a magnesium precipitation technique, was stimulated by an outward Cl- gradient (in > out). By contrast, Ox2- uptake was not enhanced by an inward Na+ or K+ transmembrane gradient. Generation of an inside-positive membrane potential by K+ in the prese...

Citrate metabolism in resting cells of Lactococcus lactis IL1403(pFL3) results in the formation of two end products from the intermediate pyruvate, acetoin and acetate (A. M. Pudlik and J. S. Lolkema, J. Bacteriol. 193:706-714, 2011). Pyruvate is formed from citrate following uptake by the transporter CitP through the subsequent actions of citrate lyase and oxaloacetate decarboxylase. The prese...