CoP nanostructures that exposed predominantly (111) crystal facets were synthesized and evaluated for performance as electrocatalysts for the hydrogen-evolution reaction (HER). The branched CoP nanostructures were synthesized by reacting cobalt(II) acetylacetonate with trioctylphosphine in the presence of trioctylphosphine oxide. Electrodes comprised of the branched CoP nanostructures deposited...

The formation of nanoparticle-polymer composites that can be processed by injection molding from superparamagnetic magnetite (Fe3O4) nanoparticles (MNPs) and the polymerizable molecule styryl acetylacetonate (stacac) is described. The best composites were created by first synthesizing MNPs in the presence of a surfactant followed by replacement with an excess of stacac monomer in a surfactant e...

Poly(L-lactic acid) microspheres loaded with holmium-166 acetylacetonate (166Ho-PLLA-MS) are a novel microdevice for intra-arterial radio-embolization in patients with unresectable liver malignancies. The neutron activation in a nuclear reactor, in particular the gamma heating, damages the 166Ho-PLLA-MS. The degree of damage is dependent on the irradiation characteristics and irradiation time i...

Reaction of the Schiff-base complex [Co(acetylacetonate-ethylenediimine)(NH3)2]+ with metmyoglobin at pH 6.5 yields a partially folded protein containing six Co(III) complexes. Although half of its alpha-helical secondary structure is retained, absorption and CD spectra indicate that the tertiary structure in both B-F and AGH domains is disrupted in the partially folded protein. In analogy to p...

White organic light emitting devices were fabricated using phosphorescent materials. The device structure was ITO/ NPB (20 nm/ DPVBi(x nm)/CDBP:5% Ir(btp)2acac(35 nm)/Alq3(y nm)/BCP(5 nm)/CsF(1 nm)/Al (150 nm), where NPB is a N,N'-bis-(1naphthyl)-N,N'–biphenyl-1,1'-biphenyl-4,4'-diamine as a hole transporting layer, DPVBi is 4,4 '-bis(2,2 -diphenylvinyl)-1,1 '-biphenyl as blue fluorescent dye, ...

Hybrid systems in which molecule-based active species are combined with nanoscale materials may offer valuable routes to enhance catalytic performances for electrocatalytic reactions. The development of rationally designed, cost-effective, efficient catalysts for the oxygen reduction reaction (ORR) is a crucial challenge for applications in fuel cells and metal-air batteries. A new hybrid ORR c...