نتایج جستجو برای: 2 amino 3 cyanopyridine
تعداد نتایج: 3476982 فیلتر نتایج به سال:
The asymmetric unit of the title compound, C(10)H(13)NO(3), contains two crystallographically independent mol-ecules with different conformations of the eth-oxy-carbonyl groups; the terminal C-C-O-C torsion angles in the two mol-ecules are 83.6 (6) and -171.1 (3)°, resulting in twisted and straight chain conformations, respectively. The crystal structure is stabilized by inter-molecular N-H⋯O, ...
The asymmetric unit of the title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))], consists of two independent mol-ecules. In each mol-ecule, the four-coordinated Sn(IV) atom exists in a distorted tetra-hedral geometry and two intra-molecular N-H⋯O hydrogen bonds with S(6) ring motifs are present. In one mol-ecule, the benzene ring of the 2-amino-3-nitro-benzoate ligand makes dihedral angles of 42...
The amide group in the title compound, C(7)H(6)ClN(3)O(3), is significantly twisted out of the plane of the benzene ring [C-C-C-O = 34.2 (5)°] whereas the nitro group is almost co-planar [O-N-C-C = 4.0 (5)°] with the ring. Intra-molecular N-H⋯O and N-H⋯Cl hydrogen bonds occur. In the crystal, the mol-ecules are linked by N-H⋯O hydrogen bonds, generating layers propagating in the ab plane.
In the title compound, C(9)H(13)NO(2)S, the mean planes of thio-phene ring [maximum deviation = 0.0042 (10) Å] and eth-oxy-carbonyl group [0.0242 (15) Å] are almost coplanar [dihedral angle between them = 0.68 (11)°]. The H atoms of the two methyl groups attached to the thio-phene ring are each disordered over two orientations with site-occupancy ratios of 0.77 (4):0.23 (4) and 0.84 (4):0.16 (4...
In the title compound, 2C(6)H(7)N(2)O(2) (+)·SO(4) (2-)·3H(2)O, there are two independent cations which are connected into N-H⋯O hydrogen-bonded dimers. In the crystal, O-H⋯O hydrogen-bonded sulfate-water sheets run parallel to (001) and are linked into a three-dimensional network via inter-molecular N-H⋯O and O-H⋯O hydrogen bonds through the 2-amino-nicotinium dimers. Further stabilization is ...
The asymmetric unit of the title salt, C3H6N3 (+)·C2F3O2 (-), contains two independent 3-amino-pyrazolium cations and two independent tri-fluoro-acetate anions. The F atoms of both anions were refined as disordered over two sets of sites, with common occupancy ratios of 0.639 (12):0.361 (12). In the crystal, the cations and anions are linked via N-H⋯O hydrogen bonds, forming chains along [100] ...
The asymmetric unit of the title compound, C(5)H(6)N(3)O(2) (+)·HSeO(4) (-), contains two monoprotonated 2-amino-3-nitro-pyridinium cations and two hydrogen selenate anions which are connected through N-H⋯O and O-H⋯O hydrogen bonds, building chains parallel to the a direction. These chains are further connected to each other by weaker C-H⋯O hydrogen-bonding inter-actions, leading to the formati...
The structure of the title compound, 2C(5)H(6)N(3)O(2) (+)·H(2)P(2)O(7) (2-), contains infinite (H(2)P(2)O(7) (2-))(n) layers stacked perpendicular to the a axis. The 2-amino-3-nitro-pyridinium cations are arranged in pairs and are anchored between these layers, linking them by N-H⋯O and C-H⋯O hydrogen-bonding and electrostatic inter-actions between anionic and cationic species to form a three-...
Synthesis of 2-[2-(2,6-dichlorophenyl)amino]phenylmethyl-3-[4-(2-substitutedphenyl-4-oxo-thiazolidinyl)aryl]-6-bromo quinazolin-4(3H)ones VIa-j have been achieved from the starting material 2-[(2,6-dichlorophenyl)amino] phenylacetic acid I to benzoxazine III, Further reaction with p-phenylindiamine and substituted aromatic aldehyde gave 2-[2-(2,6-dichlorophenyl)amino]phenyl methyl-3-(4-aminoary...
Synthesis of 2-[2-(2,6-dichlorophenyl)amino]phenylmethyl-3-[4-(2-substitutedphenyl-4-oxo-thiazolidinyl)aryl]-6-bromo quinazolin-4(3H)ones VIa-j have been achieved from the starting material 2-[(2,6-dichlorophenyl)amino] phenylacetic acid I to benzoxazine III, Further reaction with p-phenylindiamine and substituted aromatic aldehyde gave 2-[2-(2,6-dichlorophenyl)amino]phenyl methyl-3-(4-aminoary...
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