نتایج جستجو برای: نانو ceo2

تعداد نتایج: 16805  

2008
M. Ariela Peralta

Introduction Soot particles and NOx are the main pollutants from diesel engines. Good alternatives to abate these contaminants are the use of catalytic filters, which burn the soot particles, and NOx traps which adsorb the NOx during normal operation and released them during reduction cycles [1]. We recently studied BaK/CeO2 catalysts for this application[2]. Barium plays the role of NOx adsorb...

Journal: :Environmental science & technology 2009
Karen Van Hoecke Joris T K Quik Joanna Mankiewicz-Boczek Karel A C De Schamphelaere Andreas Elsaesser Paul Van der Meeren Clifford Barnes George McKerr C Vyvyan Howard Dik Van de Meent Konrad Rydzyński Kenneth A Dawson Anna Salvati Anna Lesniak Iseult Lynch Geert Silversmit Björn De Samber Laszlo Vincze Colin R Janssen

Cerium dioxide nanoparticles (CeO2 NPs) are increasingly being used as a catalyst in the automotive industry. Consequently, increasing amounts of CeO2 NPs are expected to enter the environment where their fate in and potential impacts are unknown. In this paper we describe the fate and effects of CeO2 NPs of three different sizes (14, 20, and 29 nm) in aquatic toxicity tests. In each standard t...

Journal: :Chemical communications 2005
Bo Tang Linhai Zhuo Jiechao Ge Guangli Wang Zhiqiang Shi Jinye Niu

A surfactant-free route was successfully established to synthesize CeO2 single-crystalline nanowires using H2O2 as oxidizer and template agent.

2012
Hsin-Tsung Chen

The interaction and mechanism for CO oxidation on a Ru-modified CeO2 surface have been investigated by using periodic density functional theory calculations corrected with the on-site Coulomb interaction via a Hubbard term (DFT + U). Our calculations showed that (i) the Ru dopant facilitates oxygen vacancy formation, while the Ru adatoms may suppress oxygen vacancy formation. (ii) Physisorbed C...

2014
Yu Tan Shenghan Zhang Kexin Liang

We reported Ce and its oxide-modified TiO2 nanotube arrays (TNTs) and their semiconductor properties. The TNTs were prepared by anodic oxidation on pure Ti and investigated by electrochemical photocurrent response analysis. Then, the TNT electrodes were deposited of Ce by cathodic reduction of Ce(NO3)3 6H2O. After deposition, the TNT electrodes were fabricated by anodic oxidation at E = 1.0 V(S...

2016
Qaisar Maqbool Mudassar Nazar Sania Naz Talib Hussain Nyla Jabeen Rizwan Kausar Sadaf Anwaar Fazal Abbas Tariq Jan

This article reports the green fabrication of cerium oxide nanoparticles (CeO2 NPs) using Olea europaea leaf extract and their applications as effective antimicrobial agents. O. europaea leaf extract functions as a chelating agent for reduction of cerium nitrate. The resulting CeO2 NPs exhibit pure single-face cubic structure, which is examined by X-ray diffraction, with a uniform spherical sha...

Journal: :Physical chemistry chemical physics : PCCP 2015
Xin-Ping Wu Xue-Qing Gong Guanzhong Lu

Diffusion processes and reactions of H at stoichiometric and reduced CeO2(111) surfaces have been studied by using density functional theory calculations corrected by on-site Coulomb interactions (DFT + U). Oxygen vacancies on the surface are determined to be able to significantly affect the behavior of H by modifying the charge of surface lattice O through the occurrence of Ce(3+). It has been...

2017
Edgar R. López-Mena Carlos R. Michel Alma H. Martínez-Preciado Alex Elías-Zuñiga

In this work, nanostructured CeO2 microspheres with high surface area and mesoporosity were prepared by the coprecipitation method, in absence of a template. The reaction between cerium nitrate and concentrated formic acid produced cerium formate, at room temperature. Further, calcination at 300 °C yielded single-phase CeO2 microspheres, with a diameter in the range 0.5-2.6 μm, the surface of t...

2002
Yasutaka Nagai Takamasa Nonaka Akihiko Suda Masahiro Sugiura

Oxygen storage/release (OSC) capacity is an important feature common to all three-way catalysts that enables them to efficiently remove harmful compounds such as hydrocarbons, CO and NOx in automotive exhaust gases. In this report, three types of CeO2-ZrO2 (Ce:Zr = 1:1 molar ratio) compounds with different OSC were characterized by means of XRD (X-ray diffraction) and XAFS (X-ray absorption fin...

Journal: :The journal of physical chemistry. B 2005
Garry Glaspell Lindsay Fuoco M Samy El-Shall

We report the microwave synthesis and characterization of Au and Pd nanoparticle catalysts supported on CeO2, CuO, and ZnO nanoparticles for CO oxidation. The results indicate that supported Au/CeO2 catalysts exhibit excellent activity for low-temperature CO oxidation. The Pd/CeO2 catalyst shows a uniform dispersion of Pd nanoparticles with a narrow size distribution within the ceria support. A...

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