Open AccessCCS ChemistryRESEARCH ARTICLE1 May 2021Nonmacrocyclic Iron(II) Soluble Redox Mediators Leading to High-Rate Li–O2 Battery Baoxing Wang, Xiao Xueyi Cheng, Jing Zhang, Minglei Yan, Guochang Li, Lijun Yang, Qiang Wu, Xizhang Wang and Zheng Hu Key Laboratory of Mesoscopic Chemistry MOE, Jiangsu Provincial for Nanotechnology, School Chemical Engineering, Nanjing University, 210023 Google ...

Iridium catalysts supported on anatase with high surface area showed excellent activities for the acceptor-less dehydrogenation synthesis of benzoxazoles from 2-aminophenol and primary alcohols. The catalytic activity greatly depended titania supports, iridium precursors, loading species. Catalysts JRC (Japan Reference Catalyst)-TIO-10 highest dehydrogenative reaction. Preparation using [Ir(cod...

شته مومی کلم (Brevicoryne brassicae L.)، یکی از آفات کلیدی و اقتصادی گیاهان خانواده چلیپائیان در جهان می‌باشد که اثرات مخربی بر روی کلزا (Brassica napus به همراه داشته است. این تحقیق، منظور تخمین دقیق جمعیت کلم، سه روش نمونه‌برداری (عکس‌برداری، اندازه‌گیری میانگین طول ساقه آلوده وزنی شته)‌ عنوان تیمارهای اصلی با شمارش مستقیم تیمار شاهد مرحله غنچه‌دهی، گل‌دهی غلاف‌دهی طور جداگانه، مورد مقایسه قر...

The paper summarizes new information on the formation and functioning of Ni(acac)2-based multicomponent (Ziegler) systems for oligo- polymerization ethylene. It turns out that catalytically active sites formed in these are deposited nickel-containing nanoparticles generated via interaction starting components directly reaction system. is shown activity, productivity, composition target products...

The effects of oleic acid on the activities of cytosolic HMG-CoA (3-hydroxy-3-methylglutaryl-CoA) synthase, AcAc-CoA (acetoacetyl-CoA) thiolase and AcAc-CoA synthetase, as well as microsomal HMG-CoA reductase, all enzymes in the pathway of cholesterol biosynthesis, were studied in the isolated perfused rat liver. Oleic acid bound to bovine serum albumin, or albumin alone, was infused for 4 h at...

The present article deals with a newer class of ligand bridged asymmetric complexes incorporating ancillary ligands (AL) with varying electronic characteristics: [(bpy)2Ru(II)(μ-HL(2-)) Ru(II)(bpy)2](ClO4)2·([1](ClO4)2); [(pap)2Ru(II)(μ-HL(2-))Ru(II)(pap)2](ClO4)2 ([2](ClO4)2); [(bpy)2Ru(II)(μ-HL(2-))Ru(II)(pap)2](ClO4)2 ([3](ClO4)2); [(acac)2Ru(III)(μ-HL(2-))Ru(III)(acac)2] (4) and [(bpy)2Ru(I...

The synthesis and characterization of multinuclear complexes [Pd(acac)(fcdpm)] (1), [Pd(fcdpm)(2)] (2), [Co(acac)(fcdpm)(2)] (3), [Co(fcdpm)(3)] (4) and α-alkoxy derivatives [α-OMe-fcdpm] (5), [α-OEt-fcdpm] (6), [α-OPr(n)-fcdpm] (7) and [α-OBu(n)-fcdpm] (8) (fcdpm = 5-ferrocenyldipyrromethene; acac = acetylacetone) have been described. Formation of alkoxy derivatives 5-8 takes place from highly...

Casiopeínas® is a family of copper complexes with the general formulae [Cu(N-N)(N-O)]NO3 and [Cu(N-N)(O-O)]NO3; where N-N = substituted aromatic diimine (2,2’-bipyridine (bipy) or 1,10-phenanthroline (phen)); N-O = α-aminoacidate or a peptide; and O-O = acetylacetonate (acac) or salicylaldehydate. These compounds have shown antiproliferative activity in vitro and antitumor activity in several m...