In order to study the effect of different levels of the manure and foliar application of Zn and Mn fertilizers on the quantitative and qualitative yield of soybeans (var. Williams), a factorial experiment was conducted in a randomized complete block design with three replications in 2012. Treatments involved three levels of fertilizer: manure (zero as control; six and 12 t/ha), two lev...

The oxygen-evolving complex (OEC) of photosystem II contains a Mn(4)CaO(n) catalytic site, in which reactivity of bridging oxidos is fundamental to OEC function. We synthesized structurally relevant cuboidal Mn(3)MO(n) complexes (M = Mn, Ca, Sc; n = 3,4) to enable mechanistic studies of reactivity and incorporation of μ(3)-oxido moieties. We found that Mn(IV)(3)CaO(4) and Mn(IV)(3)ScO(4) were u...

Imperfect performance equilibrium is defined as a Nash equilibrium where the players' actions may involve non-infinitesimal random errors: each player is endowed with a personal behavior pattern {his, performancefunction) under which the action that he takes depends stochastically on (i) what the player sets out to do, and (ii) the potential consequences that can accrue to him from each of his ...

Anomalous origin of left coronary artery from pulmonary artery (ALCAPA) or the Bland-White-Garland syndrome was first described in the year 1866 and postulated in 1933. It is an intriguing entity in the field of paediatrics as well as paediatric cardiology due to its varied presentation in the paediatric age group. This congenital heart anomaly is reported in less than 0.5% of all the congenita...

Time-dependent density functional theory (TDDFT) has been applied to study core excitations from 1s and 2p Mn orbitals in a series of manganese complexes with oxygen and nitrogen donor ligands. The effect of basis set and functional on the excitation energy was evaluated in detail for one complex, Mn(acac)2 x (H2O)2. The results obtained for a range of compounds, namely, [Mn(Im)6]Cl2, Mn(CH3COO...

Microorganisms catalyze the formation of naturally occurring Mn oxides, but little is known about the biochemical mechanisms of this important biogeochemical process. We used tandem mass spectrometry to directly analyze the Mn(II)-oxidizing enzyme from marine Bacillus spores, identified as an Mn oxide band with an in-gel activity assay. Nine distinct peptides recovered from the Mn oxide band of...

In the present study, two experiments were conducted to investigate the effect of Mn source on Mn transport and the expression of a Mn transporter, divalent metal transporter 1 (DMT1), in the small intestine of broilers. In Expt 1, in situ ligated duodenal loops from Mn-deficient chicks (29-d-old) were perfused with solutions containing 0-8.74 mmol Mn/l from either MnSO4, or one of two organic ...

A catalytic manganese (Mn) cluster is required for the oxidation of water in the oxygen-evolving complex (OEC) of photosystem II (PSII) in plants. Despite this essential role of Mn in generating the electrons driving photosynthesis, limited information is available on how Mn deficiency affects PSII functionality. We have here used parameters derived from measurements of fluorescence induction k...

Iron (Fe) and manganese (Mn) are essential nutrients for plants. Application of high levels of either Fe or Mn is often accompanied by relatively low levels of uptake for the other nutrient. The antagonistic relationship of these nutrient elements may occur either during absorption by roots or during translocation from roots to shoot. A greenhouse study was carried out to study the effect of so...

Manganese (Mn) toxicity in crops is a serious problem in Hawaii, especially Kauai and Oahu, where most soils are highly weathered. To devise a management strategy to control Mn toxicity, a greenhouse experiment was conducted on an acid (pH 4.4) Oxisol (Wahiawa series) having 15g·kg total Mn. Factorial combinations of lime (0, 2.0, and 4.0 g·kg CaCO3) and two composts (made from chicken manure a...