Several types of hybrid catalysts are made through mixing of 4th generation Ziegler-Natta (ZN) and (2-PhInd)2ZrCl2  metallocene catalysts using triethylaluminum (TEA) as coupling agent. Response surface methodology (RSM) is used to evaluate the interactive effects of different parameters including amounts of metallocene and TEA and temperature on metallocene loading. Analyzing the amounts of Al...

The shuttle effect of soluble lithium polysulfides (LPS), which causes rapid capacity fading, remains a lingering issue for lithium-sulfur batteries (LSBs). Herein, we report new type reactive molecule-based LPS trapper, zinc acetate-diethanolamine (Zn(OAc)2·DEA), demonstrates molecular efficiency 1.8 trapping, approaching its theoretical limit 2, is the highest trapping capability reported so ...

Although Ziegler–Natta (ZN) catalysts play a major role in the polyolefin market, true understanding of their properties at molecular level is still missing. In particular, there lack knowledge on electronic Ti sites. Theoretical calculations predict that electron density sites precatalysts correlates with activation energy for olefin insertion Ti-alkyl bond generated these after by Al-alkyls. ...

Activated carbon fiber (ACF) was modified by Zn(NO3)2, ZnCl2, and Zn(CH3COO)2), respectively, then, TiO2 loaded on the ACFs. The adsorption photocatalysis performance were explored through removal of toluene, TiO2/ACF-Ac Zn(CH3COO)2) with best toluene degradation selected. characterization results a scanning electron microscope (SEM), X-ray diffraction spectra (XRD), Fourier transform infrared ...

Dehydroaromatization of methane (DHAM) under non oxidative condition was studied over tungsten loaded HZSM-5 catalysts to produce aromatic hydrocarbons. The catalysts were prepared by impregnation method using different conditions: in neutral and acidified solution. The activity of W/HZSM-5 prepared by neutral solution and W-H2SO4/HZSM-5 prepared in acidified condition were compared. The result...

A series of transition metal complexes with two thiosemicarbazide Schiff bases, 1-(4-dimethylaminobenzyl- idene)thiosemicarbazide (ABTSC) and 1-(2-pyridincarboxyl-idene) thiosemicarbazide (TCTS) were synthesized with Co(II), Ni(II), Zn(II), Cd(II) and Ag(I) salts (chloride and acetate). These complexes were characterized by different methods including proton nuclear magnetic resonance (1HNMR),...

A series of transition metal complexes with two thiosemicarbazide Schiff bases, 1-(4-dimethylaminobenzyl- idene)thiosemicarbazide (ABTSC) and 1-(2-pyridincarboxyl-idene) thiosemicarbazide (TCTS) were synthesized with Co(II), Ni(II), Zn(II), Cd(II) and Ag(I) salts (chloride and acetate). These complexes were characterized by different methods including proton nuclear magnetic resonance (1HNMR),...

A novel series of the Co/Zn-MSN catalysts with Si/Zn molar ratio of 10 and 1, 3, 5 and 7 wt% Cobalt (denoted by CZ-X-MSN) were synthesized using post-synthesis methods. The samples were characterized by XRD, SEM, FTIR, TEM and nitrogen sorption methods. With a constant Si/Zn ratio, the increase of cobalt species from 1 to 7 wt% led to decrease the catalysts surface area from 408 m2g-1 for CZ-1-...

A series of Zn (II) complexes with nitrogen Schiff base ligands (NSB) has been synthesized from pyrrole carboxaldehyde. The prepared were fully characterized. Single crystal X-ray diffraction analysis showed various coordination modes, as monomers or helical dimers according to the number available atoms surrounding zinc cation. complex structure optimizations carried out using density function...

The operation of reforming catalysts in a fixed bed reactor undergoes high level interaction between the operating parameters and reaction mechanism. Understanding such an reduces catalyst deactivation rate. In present work, three kinds nanocatalysts (i.e., Pt/HY, Pt-Zn/HY, Pt-Rh/HY) were synthesized. catalysts’ performances evaluated for n-heptane reactions reactor. conditions applied followin...