In this study, we report the observation of oscillatory clusters in the photosensitive Belousov–Zhabotinsky reaction switching between excitable and unexcitable states. Numerical studies with a three-variable Oregonator model have been carried out in oneand two-dimensional media. Both non-flux and periodic boundaries have been characterized. Twoand three-phase clusters with standing, breathing,...

We investigate the Belousov-Zhabotinsky (BZ) reaction in an attempt to establish a basis for computation using chemical oscillators coupled via inhibition. The system consists of BZ droplets suspended in oil. Interdrop coupling is governed by the non-polar communicator of inhibition, Br2. We consider a linear arrangement of three droplets to be a NOR gate, where the center droplet is the output...

Flueric devices are fluidic devices without moving parts. Fluidic devices use fluid as a medium for information transfer and computation. A Belousov-Zhabotinsky (BZ) medium is a thin-layer spatially extended excitable chemical medium which exhibits travelling excitation wave-fronts. The excitation wave-fronts transfer information. Flueric devices compute via jets interaction. BZ devices compute...

We study a mechanism of pulse propagation failure in excitable media where stable traveling pulse solutions appear via a subcritical pitchfork bifurcation. The bifurcation plays a key role in that mechanism. Small perturbations, externally applied or from internal instabilities, may cause pulse propagation failure ~wave breakup! provided the system is close enough to the bifurcation point. We d...

In this paper, we investigated the activation energies of the aggregation−disaggregation self-oscillation induced by the Belousov-Zhabotinsky (BZ) reaction by utilizing the nonthermoresponsive polymer chain in a wide temperature range. This is because the conventional type self-oscillating polymer chain, with thermoresponsive poly(Nisopropylacrylamide) (poly(NIPAAm) main-chain covalently bonded...

The Belousov-Zhabotinsky (BZ) reaction has become the prototype of nonlinear chemical dynamics. Microfluidic techniques provide a convenient method for emulsifying BZ solutions into monodispersed drops with diameters of tens to hundreds of microns, providing a unique system in which reaction-diffusion theory can be quantitatively tested. In this work, we investigate monolayers of microfluidical...

We examine the effects of controlled, slowly varying spatial inhomogeneities on spiral wave dynamics in the light sensitive Belousov-Zhabotinsky chemical reaction-diffusion system. We measure the speed of the grain boundary that separates two spirals, the speed of the lower frequency spiral being swept away by the grain boundary, and the speed of the slow drift of the highest frequency spiral. ...

We review a series of experimental investigations on the oscillatory hydrodynamic flow appearing in a thin solution layer of the Belousov-Zhabotinsky (BZ) reaction under excitation of spiral waves. There have been many investigations to clarify the mechanism of the flow. Starting from a historical sketch, we introduce the latest findings, those closely relate to the mechanism of the oscillatory...

To detect urea content in milk powder, a nonlinear chemical fingerprint technique was developed. In our study, Belousov-Zhabotinsky oscillatory chemical reaction (B-Z) was performed using milk powder and malonic acid as main dissipative substances. The same dosage of milk powder with or without artificially added urea was introduced to “H+ + Ce4+ + 3 BrO − + malonic acid” oscillating system, re...

It was found that the periodic change of the solution viscosity and density was generated in the Belousov-Zhabotinsky (BZ) reaction. This rhythmic phenomenon was observed in both the iron catalyst [[Fe(Phen)(3)](2+)-[Fe(Phen)(3)](3+)] and the cerium catalyst [Ce(III)-Ce(IV)] system, where the solution viscosity and density were synchronized with the redox potential in the in-phase mode. However...