Azoproteins, obtained by the coupling of diazonium ions with the histidyl, tyrosyl, and lysyl groups of proteins, have continued to be materials of utility since their early investigation (1). The ease with which proteins can be modified by this procedure, the variety of aromatic amines that can be used, and the correlation that can be made between the chemical structure of the introduced group...

Nine polyisobutylene (PIB) derivatives with different end groups (chlorine, vinyl, isobutenyl, 2,2-diphenylvinyl, and carboxyl) and molecular weights (1000 to 4500 g/mol), initiated by monofunctional and aromatic bifunctional initiators were studied by atmospheric pressure photoionization mass spectrometry (APPI-MS) in both negative and positive ion modes. Consistent with previous findings, neg...

The asymmetric unit of the title salt, C10H20N3O2 (+)·C24H20B(-), contains two cations and two tetra-phenyl-borate ions. The C-N bond lengths in the central CN3 unit of the guanidinium ions range between 1.323 (2) and 1.381 (2) Å, indicating partial double-bond character. The central C atoms are bonded to the three N atoms in a nearly ideal trigonal-planar geometry and the positive charge is de...

Hierarchical nanoporous nitrogen-doped carbons were prepared from task specific ionic liquids having a bis-imidazolium motif linked with various organic groups. While ethyl chains linking the imidazolium ions afforded microporous-mesoporous carbons, long or aromatic groups resulted in microporous samples.

Citation: Zhang B-Q, Luan Y, Duan C-Q and Yan G-L (2018) Use of Torulaspora delbrueckii Co-fermentation With Two Saccharomyces cerevisiae Strains With Different Aromatic Characteristic to Improve the Diversity of Red Wine Aroma Profile. Front. Microbiol. 9:606. doi: 10.3389/fmicb.2018.00606 Use of Torulaspora delbrueckii Co-fermentation With Two Saccharomyces cerevisiae Strains With Different A...

This report describes systems which combine the structural and reactive motifs of a dinucleating terpyridine-aminomethylpyridine ligand, L, with the coordination preferences and flexibilities of particular divalent metal ions to form a series of closely related box structures in a deliberate fashion. The ligand also produces unprecedented decanickel wheel complexes. Halogen to aromatic hydrogen...

Three new [2]rotaxanes with aromatic nitrogen donors appended to the crown ether wheel have been synthesized and used as ligands to coordinate Cd(II) ions. One of these yields a new type of 2-periodic, metal organic rotaxane framework in which the wheel rather than the axle is used to link the metal nodes.