In the title complex, [V(C(13)H(15)NO(3))O(CH(3)O)(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate O,N,O'-donor ligand, derived from the condensation of salicyl-aldehyde and l-isoleucine, a vanadyl O atom, a methano-late O atom and a methanol O atom in a distorted octa-hedral geometry. The asymmetric unit contains two complex mol-ecules. In the crystal, inter-molecular O-H⋯O and C-H...
