Nowadays, there are increasingly stringent regulations requiring more and more treatment of industrial effluents to generate product waters which could be easily reused or disposed of to the environment without any harmful effects. Therefore, different advanced oxidation processes were investigated as suitable precursors for the biological treatment of industrial effluents containing phenol. We...

A detailed reaction network for the catalytic wet air oxidation (CWAO) of phenol on a CuO/ -Al2O3 catalyst is proposed in this study. The reaction network proposed accounts for all detected intermediate products of phenol oxidation overcoming the usual lumping of compounds. The model is composed by several consecutive and parallel reactions. The parameters of the model were adjusted using exper...

Catalytic wet oxidation has proved to be effective at eliminating hazardous organic compounds, such as phenol, from waste waters. However, the lack of active long-life oxidation catalysts which can perform in aqueous phase is its main drawback. This study explores the ability of bimetallic supported catalysts to oxidize aqueous phenol solutions using air as oxidant. Combinations of 2% of CoO, F...

Using dark fermentation, hydrogen can be generated from renewable organics including waste materials. Key to successful application of anaerobic fermentation is to uncouple liquid and biomass retention times in reactor system. This paper reviews reactor configurations (fixed-bed, fluidized-bed, upflow anaerobic sludge blanket and continuous stirred tank reactors) and operating processes (batch,...

In this paper, combustion of char in the riser of circulating fluidized bed was modeled using ASPEN PLUS. Since physical and chemical phenomena are involved in the process, the model integrates the two-phase hydrodynamic sub-model with the reaction sub-model derived from the literature. In the proposed model, the fluidized bed is divided into several sections and the behavior of each section wa...

the purpose of this study is to investigate the accuracy of predictions of aniline removal efficiency in a moving bed biofilm reactor (mbbr) by various methods, namely by rbf, anfis, and fuzzy regression analysis. the reactor was operated in an aerobic batch and was filled by light expanded clay aggregate (leca) as a carrier for the treatment of aniline synthetic wastewater. exploratory data an...

denitrification of high- nitrate high- salinity wastewater is difficult due to plasmolysis and inactivation of denitrifiers at high salinity conditions. in this study, the effects of salinity and empty bed contact time (ebct) on simultaneous heterotrophic and sulfur based autotrophic denitrification of synthetic wastewater were evaluated in an up flow packed bed reactor .the reactor was filled ...

operability analysis as one of the most important bridges between process design and process control helps the process designer to investigate the control issues quite early in the design stage. recently, vinson and georgakis suggested a steady state geometrical operability index as a quantitative measure for assessment of process operability. in this paper, dme fixed-bed reactor is heterogeneo...

a computational fluid dynamic (cfd) study of methanol (meoh) to dimethyl ether (dme) process in an adiabatic fixed-bed reactor is presented. one of the methods of industrial dme production is the catalytic dehydration of meoh. kinetic model was derived based on bercic rate. the parameters of this equation for a specific catalyst were tuned by solving a one-dimensional homogenous model using mat...

in this study two identical anaerobic completely mixed fluidized bed reactors with gac and sand media were employed for cod & phenol removal. at loading rate of 1.6 g phenol l-1d-1, the efficiency of phenol removal in gac & sand reactors were 97.7% & 74%, respectively. at high loading rate of phenol (6.09 g phenol i: 1d1) the efficiency of phenol removal in gac reactor was better than 95%. in g...