Abstract. Biodiesel production from waste such as wastewater sludge, palm oil mill effluent and dairy provide more sustainable approach greener energy. This paper analyzes the kinetic modelling for biodiesel scum via microwave heating transesterification. The results this study show that transesterification of is a first order which defines dependent on concentration one reactant linearly. acti...

The transesterification reaction, and in particular the methanolysis of ethyl acetate with sulfuric acid as catalyst, is used as a model reaction to study the acid-catalyzed nucleophilic addition to a carbonyl group. Continuum solvation methods (SMD and IEF-PCM) and the MPWB1K functional are used. The reaction mechanism is studied in methanol and in acetonitrile as solvents. Our results indicat...

This thesis describes methods to obtain value–added compounds from TMPturpentine obtained from the spruce, Picea abies. The methodology focuses on biotransformations using two approaches: an oxygenation approach (i.e. oxygenation of terpene hydrocarbons by cell cultures) and an esterification approach (i.e. lipase-catalysed transesterification of vinyl acetate with terpene alcohols, and a furth...

Problem Statement: The research on the production of biodiesel has increased significantly in recent years because of the need for an alternative fuel which endows with biodegradability, low toxicity and renewability. Plant oils, animal fats, microalgal oils and waste products such as animal rendering, fish processing waste and cooking oils have been employed as feedstocks for biodiesel product...

In biodiesel preparation from vegetable oils and alcohol through transesterification process in the presence of a catalyst, excess alcohol, typically 100% more than the theoretical molar requirement, is used in existing batch and continuous-flow processes in order to drive the reversible transesterification reaction to a high enough conversion rate. The excess alcohol needs to be recovered in a...

We provide a molecular description of key intermediates in the deletion of two internal eliminated sequences (IES elements), the M and R regions, during macronuclear development in Tetrahymena thermophila. Using a variety of PCR-based methods in vivo, double-strand breaks are detected that are generated by hydrolytic cleavage and correspond closely to the observed chromosomal junctions left beh...

Homogeneous catalysis is relevant for biodiesel fuel synthesis; however, it has the disadvantage of difficult separation catalyst. In present work, heterogeneous was applied rapeseed oil transesterification with methanol, while snail shells were used as a CaO content in catalyst investigated. Transesterification reactions carried out laboratory reactor, ester yield analyzed using gas chromatogr...

Glycerol is a valuable byproduct in biodiesel production by transesterification, soap manufacturing by saponification as well as hydrolysis reaction. The purity of glycerol obtained is low due to the presence of impurities such as remaining catalyst, water, soaps, salts and esters formed during the reaction. Purification of glycerol as well as the conversion of glycerol into valuable products h...

Present study demonstrated the preparation of MCM-41 as a support for the immobilization of Candida rugosa lipase by the physical adsorption technique. The lipase immobilized MCM-41 has been characterized by scanning electron microscopic and FTIR techniques. At pH 6, maximum lipase immobilization (250 mg/g) on MCM support has been observed and the immobilized lipase was employed as biocatalyst ...