نتایج جستجو برای: torsion unit
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The title compound, C16H20N2O2S2, crystallizes with two enanti-omers (A and B) in the asymmetric unit. The most noticeable difference between these two mol-ecules is the relative orientation of the benzo-thia-zole rings, with S-C-C-S torsion angles of -19.4 (2) (mol-ecule A) and 100.6 (1)° (mol-ecule B). The amide structure of the thia-zolidinone rings leads to inter-molecular hydrogen-bonded d...
The title compound, 2C(21)H(34)N(4)O(3)S(2+)·4I(-)·5H(2)O, was prepared exclusively as the E isomer by methyl-ation of the corresponding N-phenyl-pyridin-4-amine. There are two symmetry-independent mol-ecules in the asymmetric unit with no significant differences in bond lengths and angles. The aromatic rings are not coplanar with the pyridin-4-imine groups, as indicated by the C-N-C-C torsion ...
The asymmetric unit of the title compound, C(19)H(12)Cl(2)O, contains four independent mol-ecules, which can be divided into two pairs of mol-ecules with close values of the C-C(=O)-C=C torsion angles in each pair, viz. 165.12 (16) and 165.68 (15)° in one pair, and -164.66 (15) and -164.81 (15)° in the other pair. The crystal packing exhibits short inter-molecular Cl⋯Cl contacts of 3.362 (1) Å.
The title compound, C(11)H(11)N(3), was synthesized as part of our research into functionalized pyrimidines. It crystallizes with two independent mol-ecules in the asymmetric unit that differ only in the twist between the two aromatic rings; the torsion angles between the rings are 29.9 (2) and 45.1 (2)°. The crystal packing is dominated by inter-molecular N-H⋯N hydrogen bonds between independe...
torsion and infarction of the greater omentum are two rare clinical situations which present as an acute abdomen. nevertheless, knowledge concerning these two problems can help the surgeon in proper diagnosis and treatment. since the first report on primary torsion by eitel in 1899, a few hundred more have been reported and some collective reviews published to date. in this study we will presen...
The title compound, C(26)H(36)N(2)O(2), was prepared by Horner olefination of p-dihexyl-amino-benzaldehyde and diethyl p-nitro-benzyl-phospho-nate. It crystallizes with two independent mol-ecules in the asymmetric unit. Both have similar geometries of the π-systems but the conformations of all hexyl chains are different. Whereas one hexyl chain of the first mol-ecule shows the typical all-anti ...
Background The aim of this study was to determine oxidative stress (OS) parameters after testicular torsion/detorsion in adult rats. MaterialsAndMethods In this experimental study, male adult Wistar rats were divided into four groups, each consisting of seven animals: group I-one hour right testicular torsion with subsequent orchiectomy, group II-one hour right testicular torsion followed by de...
Torsion and infarction of the greater omentum are two rare clinical situations which present as an acute abdomen. Nevertheless, knowledge concerning these two problems can help the surgeon in proper diagnosis and treatment. Since the first report on primary torsion by Eitel in 1899, a few hundred more have been reported and some collective reviews published to date. In this study we will p...
In the projects Smartblades and 2 a full-scale 20 m rotor blade for NREL CART3 wind turbine was designed, built tested. The intended to have strong bending–torsion coupling. By means of experiments, proof technology in question supposed be provided. experimental work accompanied by simulations. aim paper describe publish reference finite element model blade. validation procedure is presented, a...
In this note we investigate the hypercentral units in integral group rings ZG, where G is not necessarily torsion. One of the main results obtained is the following (Theorem 3.5): if the set of torsion elements of G is a subgroup T of G and if Z2(U) is not contained in CU (T ), then T is either an Abelian group of exponent 4 or a Q∗ group. This extends our earlier result on torsion group rings.
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