TiO2 günlük hayatta kullanılan önemli kimyasallardan biridir. Fotokatalitik aktivitenin keşfi ile kullanım alanı daha da genişlemiştir. son yıllarda kendi kendini temizleyen kumaş çalışmalarında yaygın olarak kullanılmaktadır. Fotoaktif özellik göstermesi ve üzerindeki organik grupları ayrıştırması için, UV ışığı uyarılır. Sol-jel yöntemiyle hazırlanan nano boyutlu (NB TiO2), çeşitli türleri üz...

In this study, the effects of treatment with Ag, Au, Cu, Pd, CeO2, CuO, TiO2 and ZnO nanoparticles (NPs) on plant secondary metabolism were tested using an untargeted metabolomic approach in cell suspension cultures Hypericum perforatum L. Variations accumulation metabolites observed after exposure to NPs. Overall, number compounds increased by metal NPs was higher than that oxides. Among oxide...

For a solar thermal system, increasing the heat transfer area can increase the output temperature of the system. However, this approach leads to a bigger and bulkier collector. It will then increase the cost and energy needed to manufacture the solar collector. This study is carried out to estimate the potential to design a smaller solar collector that can produce the same desired output temper...

In situ IR and mass spectrometry evidence for the catalytic formation on SiO2 and TiO2 surfaces of glycine oligomers (poly-Gly) up to 16 units long by successive feeding with monomers from the vapor phase is presented. Parallel experiments carried out on hydroxyapatite resulted in the unreactive adsorption of Gly, thus indicating that the oligomerization was specifically catalyzed by the surfac...

The interaction of the rutile TiO2(110) surface with tetraethyl orthosilicate (TEOS) in the pressure range from UHV to 1 mbar as well as the TEOS-based chemical vapor deposition of SiO2 on the TiO2(110) surface were monitored in real time using near-ambient pressure X-ray photoelectron spectroscopy. The experimental data and density functional theory calculations confirm the dissociative adsorp...

The photocatalytic degradation of organic compounds of olive mill wastewater (OMWW) was investigated by using core-shell-shell Fe3O4/SiO2/TiO2 nanoparticles as catalyst. The preparation of nanoparticles was performed by coating onto magnetic nanoparticles a SiO2 layer, using Stober method and TiO2 layer, using sol-gel method. The photo catalyst was characterized by dynamic light scattering (DLS...

In this study, a radial basis function (RBF) neural network with three-layer feed forward architecture was developed to effectively predict the viscosity ratio of different ethylene glycol/water based nanofluids. A total of 216 experimental data involving CuO, TiO2, SiO2, and SiC nanoparticles were collected from the published literature to train and test the RBF neural network. The parameters ...

The fate of nanoparticles (NPs) in soil under relevant environmental conditions is still poorly understood. In this study, the mobility two metal-oxide (CuO and TiO2) contrasting agricultural soils was investigated water-saturated columns. transport TiO2 CuO-NPs were assessed six with three different textures (from sand to clay) contrasted organic matter (OM) contents for each texture. very low...

Raman spectroscopy is known as a powerful technique for solid catalyst characterization as it provides vibrational fingerprints of (metal) oxides, reactants, and products. It can even become a strong surface-sensitive technique by implementing shell-isolated surface-enhanced Raman spectroscopy (SHINERS). Au@TiO2 and Au@SiO2 shell-isolated nanoparticles (SHINs) of various sizes were therefore pr...