The processes of oxidative thermolysis bismuth tartrates [Bi(NO3)(C4H4O6)]·3H2O and BiC4H3O6·H2O precipitated from nitrate solutions was studied by the methods X-ray diffraction, thermal analysis, IR spectroscopy chemical analysis. staging transformation determined. Morphological studies initial precursors final products their transformations were carried out. expediency obtaining fine-crystal ...

The synthesis of germanium nanoparticles has been carried out, thanks to the design of novel aminoiminate germanium(II) precursors: (ATI)GeZ (with Z = OMe, NPh2, and ATI = N,N'-diisopropyl-aminotroponiminate) and (Am)2Ge (Am = N,N'-bis(trimethylsilyl)phenyl amidinate). These complexes were fully characterized by spectroscopic techniques as well as single crystal X-ray diffraction. The thermolys...

Vapour thermolysis processes of copper(I1) bis-chelate complexes with different p-diketones in the 160640°C temperature range were studied by using the high-temperature source of a molecular beam with mass spectrometric recording of the gas phase composition directly at the outlet from the thermal reactor. Schemes of a heterogeneous decomposition of these compounds vapour were suggested on the ...

BACKGROUND The coordination chemistry of cadmium(II) with diamine ligands is of particular interest. The most common structure around cadmium(II) center in their complexes is tetrahedral, that is due the octet rule obeyed. Nevertheless, five and six-coordinated complexes are also well known. Now a day, many cadmium(II) complexes with chelate ligands were synthesized for their structural or appl...

The chemical pathway responsible for the conversion of the organotitanium compound tetraneopentyltitanium to titanium carbide has been studied under chemical vapor conditions and on single crystals in ultra-high vacuum. For every equivalent of TiNp4 consumed in the deposition process, 3.28 equiv of neopentane and 0.16 equiv of isobutane are produced; other organic species are also formed but in...

Hydrazine borane (N(2)H(4)BH(3)) is the novel boron- and nitrogen-based material appearing to be a promising candidate in chemical hydrogen storage. It stores 15.4 wt% of hydrogen in hydridic and protic forms, and the challenge is to release H(2) with maximum efficiency, if possible all hydrogen stored in the material. An important step to realize this ambitious goal is to synthesize HB with hi...