A facile method, i.e., nonsolvent assisted electrospraying, is proposed to fabricate hierarchically porous microspheres. The pore size on the microsphere surface ranges from a few tens to several hundred nanometers. Thermally and nonsolvent induced phase separation as well as breath figure is responsible for the formation of the hierarchical structures with different nano-sized pores. The nonso...

Phase-separation is commonly observed in multimetallic nanomaterials, yet it not well understood how immiscible elements distribute a thermodynamically stable nanoparticle. Herein, we studied the phase-separation of Au and Rh nanoparticles using electron microscopy tomography techniques. The were thermally annealed to form structures. HAADF-STEM EDS characterizations reveal that segregate into ...

To better engineer small-diameter blood vessels, a few types of novel scaffolds were fabricated from biodegradable poly(L-lactic acid) (PLLA) by means of thermally induced phase separation (TIPS) techniques. By utilizing the differences in thermal conductivities of the mold materials, the scaffolds with oriented gradient microtubular structures in axial or radial direction were created using be...

We analyze the phase shift induced in an amplitude-modulated laser beam propagating through a water dispersion of graphene oxide sheets in a fiber-to-fiber U-bench. This phase shift arises from the thermally induced nonlinear refraction in the sample. The system exhibits strong optical limiting performance for weak continuous-wave signals. A theoretical model including beam propagation and ther...

in this study, porous scaffolds from poly(d,l-lactic acid) have been prepared via liquid- liquid phase separation method in ternary system of polymer-1,4-dioxane-water. polymer dissolved in dioxane in 1.5, 2.5 and 5 % wt/v and the solvent/non-solvent ratios were 13/87, 15/85 and 17/83. cloud point curves prepared by visual turbidometry. in order to obtain porous scaffolds with inter-connected p...

Shape Memory Alloys (SMAs) undergo stress and temperature induced reversible diffusionless crystalline phase transformations between a high synmaetry phase (austenite) stable at high tenlperatures and low stresses, and a low symmetry phase (martensite) stable at low temperatures and high stresses. Unusual macroscopic effects arise from these crystallographic changes, chiefly shape memory and su...