Three copper(I) dithiocarbamate–phosphine complexes of the general formula Cu(PPh3)2L were synthesized by metathesis reactions potassium salt dithiocarbamate ligand L and precursor complex Cu(PPh3)2NO3 in an equimolar ratio. represents N,N?-bis(2,6-dimethylphenyl)formamidine L1 1, N,N?-bis(2,6-disopropylphenyl) formamidine L2 2, N,N?-dimesitylformamidine L3 3. The single-crystal X-ray structure...