نتایج جستجو برای: task specific ionic liquids

تعداد نتایج: 1346587  

Journal: :Chemistry and physics of lipids 2016
Inkeri Kontro Kirsi Svedström Filip Duša Patrik Ahvenainen Suvi-Katriina Ruokonen Joanna Witos Susanne K Wiedmer

The effects of ionic liquids on model phospholipid membranes were studied by small-angle X-ray scattering, dynamic light scattering (DLS) and zeta potential measurements. Multilamellar 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine liposomes and large unilamellar vesicles composed of l-α-phosphatidylcholine (eggPC) and l-α-phosphatidylglycerol (eggPG) (80:20mol%) or eggPC, eggPG, and choleste...

Journal: :Chemical communications 2013
Kaitlin D Beare Alexander K L Yuen Anthony F Masters Thomas Maschmeyer Christopher S P McErlean

A major limitation of on-water catalysis has been the need for liquid reactants to enable emulsification. We demonstrate that ionic liquids are compatible with on-water catalysis, enabling on-water catalysed reactions for otherwise unreactive solid-solid systems. The unique solvation properties of ionic liquids dramatically expands the scope of on-water catalysis.

Journal: :physical chemistry research 0
hemayat shekaari physical chemistry department, university of tabriz, tabriz, iran mohammed taghi zafarani-moattar university of tabriz seyyedeh narjes mirheydari university of tabriz

in recent years, ionic liquids have been used in pharmaceutical processes. therefore, having a deep insight into the ion association behavior of ionic liquids in the presence of a drug is of particular importance. so, in this work, the molar conductivities of the ionic liquids, 1-alkyl-3-methylimidazolium bromide, [cnmim]br (n = 4, 6 and 8) in various concentrations of aspirin (asa) in acetonit...

Journal: :Dalton transactions 2014
Nico E A Cousens Leah J Taylor Kearney Matthew T Clough Kevin R J Lovelock Robert G Palgrave Susan Perkin

A range of ionic liquids containing dialkylimidazolium cations and halobismuthate anions ([BiBr(x)Cl(y)I(z)](-) and [Bi2Br(x)Cl(y)I(z)](-)) were synthesised by combining dialkylimidazolium halide ionic liquids with bismuth(III) halide salts. The majority were room temperature liquids, all with very high densities. The neat ionic liquids and their mixtures with 1-butyl-3-methylimidazolium bis(tr...

Journal: :Molecules 2015
Mahesh K Potdar Geoffrey F Kelso Lachlan Schwarz Chunfang Zhang Milton T W Hearn

Over the past decade, a variety of ionic liquids have emerged as greener solvents for use in the chemical manufacturing industries. Their unique properties have attracted the interest of chemists worldwide to employ them as replacement for conventional solvents in a diverse range of chemical transformations including biotransformations. Biocatalysts are often regarded as green catalysts compare...

2011
Nicola Manini Pietro Ballone Daniele Dragoni

Journal: :Proceedings of the National Academy of Sciences of the United States of America 2015
Matthew A Gebbie Howard A Dobbs Markus Valtiner Jacob N Israelachvili

Electrolyte solutions with high concentrations of ions are prevalent in biological systems and energy storage technologies. Nevertheless, the high interaction free energy and long-range nature of electrostatic interactions makes the development of a general conceptual picture of concentrated electrolytes a significant challenge. In this work, we study ionic liquids, single-component liquids com...

Journal: :Physical chemistry chemical physics : PCCP 2011
Sheila N Baker Hua Zhao Siddharth Pandey William T Heller Frank V Bright Gary A Baker

A fluorescence energy transfer "de-quenching" assay was implemented to follow the equilibrium unfolding behaviour of site-specific tetramethylrhodamine-labelled yeast cytochrome c in aqueous ionic liquid solutions; additionally, this approach offers the prospect of naked eye screening for biocompatible ion combinations in hydrated ionic liquids.

Journal: :Chemical communications 2012
Ana B Pereiro João M M Araújo Filipe S Oliveira Carlos E S Bernardes José M S S Esperança José N Canongia Lopes Isabel M Marrucho Luís P N Rebelo

This work explores the possibility of increasing the ionicity of ionic liquids via the solubilization of inorganic salts in their midst. The resulting purely ionic media-distinct ionic liquid plus inorganic salt mixtures-are liquid in an extensive concentration range and can be aptly denominated High Ionicity Ionic Liquids (HIILs).

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