We describe the electrochemical determination of oxidative damaged DNA by using a nanocarbon film electrode combined with a high performance liquid chromatography (HPLC) system. The nanocarbon film was formed by employing the electron cyclotron resonance sputtering method, and has a nano-crystalline sp(2) and sp(3) mixed bond structure with an atomically flat surface. This film electrode provid...

A novel method was used to prepare the nano-composite by assembling nanogold (NG) particles on the multiwall carbon nanotubes (MWNTs) surface. The nano-composite could be immobilized on a glassy carbon (GC) electrode to get a novel modified electrode. The electrode can easily immobilize the horseradish peroxidase (HRP) molecules to construct a reagentless biosensor. The NG particles in the comp...

The oxygen reduction reaction (ORR) in 0.1 M NaOH on platinum single crystal electrodes has been studied using hanging meniscus rotating disk electrode configuration. Basal planes and stepped surfaces with (111) and (100) terraces have been employed. The results indicate that the Pt(111) electrode has the highest electrocatalytic activity among all the studied surfaces. The addition of steps on...

The interface of a 1 : 2 molar choline chloride/ethylene glycol deep eutectic solvent with a glassy carbon electrode has been investigated by polarization modulation reflection-absorption spectroscopy (PM-IRRAS). Temporal spectral changes at open circuit potential show the experiments to be surface sensitive and indicate slow adsorption of electrolyte molecules on the electrode surface. In situ...

Jeschull, F. 2017. Polymers at the Electrode-Electrolyte Interface. Negative Electrode Binders for Lithium-Ion Batteries. Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 1490. 84 pp. Uppsala: Acta Universitatis Upsaliensis. ISBN 978-91-554-9855-9. We are today experiencing an increasing demand for high energy density storage devices like the l...

We herein report an ultrasensitive electrochemical sensing strategy for picomole determination of glutathione by using two gold electrodes and two complementary thiolated oligonucleotides. When one gold electrode whose surface has been immobilized with one of the two oligonucleotides is immersed in a glutathione solution for detection, due to the ligand release effect, the oligonucleotides will...

The effect of the presence of an Fe-Cr alloy metallic interconnect on the performance and stability of La(0.8)Sr(0.2)MnO3 (LSM) oxygen electrodes is studied for the first time under solid oxide electrolysis cell (SOEC) operating conditions at 800 °C. The presence of the Fe-Cr interconnect accelerates the degradation and delamination processes of the LSM oxygen electrodes. The disintegration of ...

in this paper, dissimilar resistance spot welding of aisi 1075 eutectoid steel to aisi 201 stainless steel is investigated experimentally. for this purpose, the experiments are designed using response surface methodology and based on four-factor, five-level central composite design. the effects of process parameters such as welding current, welding time, cooling time and electrode force are inv...

developing simple, sensitive and selective sensing systems for dopamine is important due to its biological significance. in this work, a silver nanoparticles-modified carbon paste electrode (agnps-cpe) has been constructed and used to detect of dopamine (da) in the simultaneous presence of ascorbic acid (aa) and uric acid (ua) at neutral ph 7.0 by cyclic voltammetry. the modified electrode show...

In this theoretical work, we present for the first time voltammetric results of a surface multistep electron transfer mechanism that is associated with a preceding chemical reaction that is linked to the first electron transfer step. The mathematical model of this so-called “surface CEE mechanism” is solved under conditions of square-wave voltammetry. We present relevant set of results portrayi...