Recent studies have shown that it is possible to electrodeposit a range of materials, such as Cu, Ag and Ge, from various supercritical fluids, including hydrofluorocarbons and mixtures of CO2 with suitable co-solvents. In this perspective we discuss the relatively new field of electrodeposition from supercritical fluids. The perspective focuses on some of the underlying physical chemistry and ...

A measuring method for the distribution behavior between supercritical carbon dioxide and water by a microchip was developed. A surface modification of the microchannel by dichlorodimethylsilane induced a spontaneous phase separation of the supercritical carbon dioxide and aqueous phases in the microchip. The maximum contact time of the aqueous phase to the supercritical carbon dioxide phase wa...

This study examined the effects of sub- and supercritical water pretreatments on the physicochemical properties of crab shell α-chitin and its enzymatic degradation to obtain N,N'-diacetylchitobiose (GlcNAc)2. Following sub- and supercritical water pretreatments, the protein in the crab shell was removed and the residue of crab shell contained α-chitin and CaCO3. Prolonged pretreatment led to α...

The present study is aimed at a detailed analysis of supercritical water structure based on the combination of experimental vibrational spectra as well as molecular modeling calculations of isolated water clusters. We propose an equilibrium cluster composition model where supercritical water is considered as an ideal mixture of small water clusters (n=1-3) at the chemical equilibrium and the vi...

The pulmonary route has recently attracted attention as a noninvasive administration route for peptide and protein drugs, and an insulin powder for inhalation was approved by authorities in Europe and the USA. The present study examined usefulness of insulin and gene powders for systemic and local inhalation therapy. We prepared several dry insulin powders by spray drying to examine the effect ...

Trichlorocarbanilide has widely been used in cosmetics and household products, but the extremely low solubility of trichlorocarbanilide in water constrains the development of water-based products. In order to enhance the bioavailability, trichlorocarbanilide were micronized using supercritical fluid. Supercritical carbon dioxide was selected due to relatively low critical temperature and the ra...

We describe a finite-dimensional reduction method to find solutions for a class of slightly supercritical elliptic problems. A suitable truncation argument allows us to work in the usual Sobolev space even in the presence of supercritical nonlinearities: we modify the supercritical term in such a way to have subcritical approximating problems; for these problems, the finite-dimensional reductio...

A transparent wet gel was obtained in a few minutes at room temperature by adding an aqueous phosphoric acid solution of appropriate concentration to boehmite nanofiber sol. After aging and supercritical carbon dioxide drying, low bulk density aerogels with visible light transmittance over 90% 10 mm thickness were obtained. These exhibited high Young’s modulus transmittance, while having the sa...

Graphene aerogel (GA) samples, prepared by the Sol-Gel method, were tested under quasi-static and dynamical compression, characterized via surface area analyzer scanning electron microscopy. The results show that drying method has a significant influence on sample’s microstructure as well its mechanical compression properties. supercritical CO2 dried sample notable higher specific area, strengt...

Vacuum drying of Salicornia herbacea L. was performed at different drying temperatures (50, 60, 70, and 80°C) to evaluate the drying characteristics and the effect of drying temperatures on the quality of Salicornia. As the drying temperature increased, the drying time decreased significantly (P< 0.05). The drying rate decreased with decrease in moisture content and increase in drying time. On ...