The purpose of this evaluation was to provide an objective evaluation of the use of supercritical carbon dioxide (CO,) as an alternative technology for spray applied in wood finishing processes using reduced solvent formulations. Union Carbide has pioneered this technology under the UNICARBTM trademark. In the UNICARBTM process, the solvent-like properties of supercritical CO, are employed to r...

Supercritical fluid extraction was used to extract the alkaloid N-[7-(3',4'-methylenedioxyphenyl)-2(Z),4(Z)-heptadienoyl]pyrrolidine from leaves of Piper amalago L. A three-level orthogonal array design matrix, OAD OA9(34), was used for optimization of the parameters of supercritical extraction of the alkaloid, employing supercritical carbon dioxide: extraction time (20, 40, and 60 min), temper...

Aerosol solvent extraction system (ASES) was used to prepare micro-particle of acetaminophen by supercritical carbon dioxide as an anti-solvent. Experiment was carried out at various temperatures, pressures, solvents and investigated the effects of these parameters on particle size, size distribution and morphology by SEM and laser diffraction particle size analyzer. It seems that the choice of...

Chokeberry (Aronia melanocarpa (Michx.) Elliot) is a fruit with exceptionally high levels of phenolic compounds which are accumulated mainly in the peel; hence, the majority remains in the leftovers after juice production. Extraction with the use of carbon dioxide in supercritical conditions was used to isolate phenolic compounds from the pomace. The effect of the process parameters (temperatur...

This study examined the supercritical fluid extraction of wheat germ oil. The effects of pressure (200-300 bar at 40 degrees C) and extraction time on the oil quality/quantity were studied. A comparison was also made between the relative qualities of material obtained by SFE and by organic solvent extraction. The extracts were analyzed for alpha-tocopherol and polyunsaturated fatty acid content...

The black walnut, Junglas nigra, is indigenous to eastern North America, and abscission of its fruit occurs around October. The fruit consists of a husk, a hard shell, and kernel. The husk is commonly discarded in processing, though it contains phenolic compounds that exhibit antioxidant and antimicrobial properties. For this study, black walnut husks were extracted using supercritical carbon d...

The kinetics of the extraction of tea seed oil with supercritical CO2 was studied. A kinetic model of the extraction of tea seed oil using supercritical CO2 was developed on the basis of the differential mass balance to simulate the extraction process. The model could simulate the distribution of the solute concentration in CO2 inside the extraction bed as a function of extraction time and heig...

Supercritical carbon dioxide (SC-CO2 ) has been used for the first time as a reaction medium for the dehydration of glycerol to acrolein catalyzed by a solid acid. Unprecedented catalyst stability over 528 hours of time-on-stream was achieved and the rate of coke deposition on the zeolite catalyst was the lowest among extensive previous studies, showing potential for industrial application. Cok...

Dioxide and Extraction Efficiency of Astaxanthin Extraction from H. pluvialis Duangkamol Ruen-ngam, Artiwan Shotipruk, Motonobu Goto, and Prasert Pavasant∗ Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Thailand Bioelectrics Research Center, Kumamoto University, Japan Corresponding author, email: [email protected] (P. Pavasant) and [email protected] ...

The state of aggregation of water dissolved in supercritical carbon dioxide has been investigated under isobaric heating (T=40-340°C, P=250 bar) using infrared absorption and Raman scattering spectroscopies. Quantitative analysis of experimental spectra has shown that below 100°C, water exists only in its monomeric form (solitary water surrounded by CO2 molecules) whereas H-bonded species, name...