نتایج جستجو برای: sulfones
تعداد نتایج: 1199 فیلتر نتایج به سال:
The cyclo-addition reaction of diazomethane with a,/3-unsaturated sulfones is described. Divinyl sulfone and phenyl vinyl sulfone give 1or 2-pyrazolines depending on the reaction conditions. cisand /rans-l,2-Bis(methylsulfonyl)ethene form pyrazolines, which on reaction with either triethylamine or excess of diazomethane lead to substituted pyrazoles. The addition of diazomethane to doüble bonds...
The cyclo-addition reaction of diazomethane with a,/3-unsaturated sulfones is described. Divinyl sulfone and phenyl vinyl sulfone give 1or 2-pyrazolines depending on the reaction conditions. cisand /rans-l,2-Bis(methylsulfonyl)ethene form pyrazolines, which on reaction with either triethylamine or excess of diazomethane lead to substituted pyrazoles. The addition of diazomethane to doüble bonds...
Sulfones are one of the most important classes of agricultural fungicides. To discover new lead compounds with high antibacterial activity, a series of new sulfone derivatives were designed and synthesized by introducing the aroxymethyl moiety into the scaffold of 1,3,4-oxadiazole/thiadiazole sulfones. Antibacterial activities against three phytopathogens (Xanthomonas oryzae pv. oryzae, Ralston...
Previously, we introduced a series of anion-binding interpenetrated double-cages based on phenothiazine and its mono- and di-S-oxygenated derivatives. Here, we complete the structural comparison of the three related assemblies by an X-ray single crystal analysis of the sulfone derivative. We further show that the three palladium cages coexist in solution upon post-assembly mixing due to the ver...
In contrast to vinylsulfonates and vinylsulfones, vinylsulfonamides are unreactive in Pd-catalyzed oxidative Heck-coupling reactions with acetanilides. This limitation has been resolved by using a C?H-activation protocol based on Ru?Cu?Ag-catalysis. Overall, the Ru?Cu?Ag-catalyzed conditions turned out be more reliable showed better reproducibility than C?H-activation. The coupling products thu...
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