A three-coordinate Cu-NR(2) system (R = p-tolyl) supported by the anionic bis(phosphino)borate ligand [Ph(2)B(CH(2)P(t)Bu(2))(2)](-) has been isolated and structurally characterized in both its anionic Cu(I) and neutral (formally) Cu(II) oxidation states. A large rate constant for the self-exchange electron-transfer reaction (k(S) >or= 10(7) M(-1) s(-1)) makes this system a functional model for...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

Magnetic damping of the spin, the decay rate from the initial spin state to the final state, can be controlled by the spin transfer torque. Such an active control of damping has given birth to novel phenomena like the current-driven magnetization reversal and the steady spin precession. The spintronic devices based on such phenomena generally consist of two separate spin layers, i.e., free and ...

The detection of free radicals and related species has attracted significant attention in recent years because of their critical roles in physiological and pathological processes. Among the methods for the detection of free radicals, electron spin resonance (ESR) coupled with the use of the spin trapping technique has been an effective approach for characterization and quantification of these s...

We present an experimental and theoretical study of a scalar atomic magnetometer using an oscillating field-driven Zeeman resonance in a high-density optically pumped potassium vapor. We describe an experimental implementation of an atomic gradiometer with a noise level below 10 fT Hz−1/2, fractional field sensitivity below 10−9 Hz−1/2, and an active measurement volume of about 1.5 cm3. We show...

We show that the fluctuation-dissipation relation can be established for a class of stochastic dynamics that lack detailed balance. This class comprises lattice spin models whose time evolution is governed by a master equation with a one-spin-flip transition rate having the up-down symmetry. The relation is obtained by the introduction of a multiplicative perturbation of the transition rate, wh...

The renormalization group formalism was applied to calculate the spinlattice relaxation rate T 1 of a well-defined magnetic moment in the neighborhood of a spin degenerate Anderson impurity. In the Kondo regime, T 1 in function of the temperature T presents a peak at the Kondo temperature Tk; for T ≪ Tk, the system behaves as a heavy Fermy liquid, with an enhanced density of states, which incre...

Glitches are common phenomena in pulsars. After each glitch, there is often a permanent increase in the pulsar’s spin-down rate. Therefore a pulsar’s present spin-down rate may be much higher than its initial value and the characteristic age of a pulsar based on its present spin-down rate and period may be shorter than than its true age. At the same time, the permanent increase of its spindown ...

The magnetic field dependence of the proton-spin-lattice relaxation rate in rotationally immobilized proteins shows that the one-dimensional character of the protein primary structure causes a dramatic increase in the population of low-frequency motions from 10 kHz to 20 MHz. As a consequence, the probability and rate at which functionally critical conformational states are thermally sampled in...