The photooxidation of thebaine (3) with a sun lamp affords two main products: hydrodibenzofuran 10 (major) and benzofuran 11 (minor). The latter compound becomes predominant if a Hg lamp is used instead of a sun lamp. The formation of 10 proceeds via an endoperoxide intermediate that undergoes oxidation at the nitrogen atom. Protection of the nitrogen either by protonation or quaternization pre...

the objective of this work was to study the effects of tillage and liquid manure applications on some physical and chemical properties as well as on the carbon and nitrogen mineralization potential of a meadow soil. our results indicated that tillage and manure applications had no effect on the concentration of cu, mn, total n and organic c in 0-15 cm layer of soil after 15 years of treatment. ...

The presence of organic compounds and high amount of secondary metabolites (polysaccharides, phenolic component, etc.) in mosses cause difficulties in DNA extraction that are followed by problems in PCR reactions. In lower plants, various methods have been used for DNA extraction including silica gel and different commercial kits. These methods mostly use hazardous (like phenol or liquid nitrog...

nano fillers are part of new studies to enhance various properties of fluids and solids. for example, adding nanoparticles as an enforcement in nanocomposites or as an additive to improve thermal or electrical properties in nano-fluids are of extreme importance in science and industry. there are numerous methods to uniformly disperse nanoparticles in fluid and solid phase. one of the well-used ...

BACKGROUND The demonstration of tissue-bound immunoreactants by direct immunofluorescence microscopy (DIF) is a valuable parameter in the diagnosis of various autoimmune and immunecomplex-mediated skin diseases. For preservation of tissue-bound immunoreactants, biopsies are usually fresh-frozen in liquid nitrogen or transported in Michel's fixative. But even optimally preserved tissue specimens...

Nitrogen is produced mainly from its most abundant source, the air, using three processes: membrane, pressure swing adsorption (PSA) and cryogenic. The most common method for evaluating a process is using the selection diagrams based on feasibility studies. Since the selection diagrams are presented by different companies, they are biased, and provide unsimilar and even controversial results. I...

We develop an approach to utilize anisotropic metamaterials to solve one of the fundamental problems of modern plasmonics--parasitic scattering of surface waves into free-space modes, opening the road to truly two-dimensional plasmonic optics. We illustrate the developed formalism on the examples of plasmonic refractor and plasmonic crystal, and discuss limitations of the developed technique an...

We report on a measurement of the absorption length of scintillation light in liquid argon due to dissolved nitrogen at the part-per-million (ppm) level. We inject controlled quantities of nitrogen into a high purity volume of liquid argon and monitor the light yield from an alpha source. The source is placed at different distances from a cryogenic photomultiplier tube assembly. By comparing th...

with amperometric detection. It has been shown elsewhere that the selectivity of this method is sufficient to separate the potential organic impurities; that is, synthesis byproducts and a specified degradation product from the drug substance (3). The objective of this article is to demonstrate that this method’s suitability for stability testing can be evaluated easily by performing HPLC with ...

In order to study effects of nitrogen fertilization and cultivars on some of traits of different barley an experiment was conducted at Isfahan in 2012. The experimental was split plot in a randomized complete block design with three replications. In this experiment, different levels of nitrogen in the main plots included four levels (0, 50, 100 and 150 N kg/ha (urea)) and barley cultivars inclu...