Three Lewis base variations of the synthetically useful aluminate [L x Li(TMP)((i)Bu)Al((i)Bu)2], where L is TMPH, Et3N or PhC(=O)N(i)Pr2, are reported, together with the reaction of the benzamide complex with 1,4-dioxane, which surprisingly leads to fragmentation of the cyclic ether and capture of its alkoxy vinyl ether residue within a novel dilithium dialuminium hexaalkyl aggregate.

A clean-route synthesis of Zn-Al-hydrotalcites (Zn-Al-LDHs) using zinc oxide and sodium aluminate solution has been developed. The as-obtained materials were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). The effects of metal ions at different molar ratios on the performance of hydrotalcites were discussed. The ...

Aluminum metal is produced by the electrolytic reduction of aluminum oxide (Al2O3), mainly extracted from bauxite ore digested in a hot caustic soda solution. This solution is supersaturated with respect to sodium aluminate and silicate, which react together to form sodalite (3[Na2O⋅Al2O3⋅2SiO2⋅2H2O]⋅Na2CO3) at high temperatures. Heat exchanger tubes are scaled with this compound, which serious...

The Bayer Process (for alumina) as we know it today involves two steps: • The pressure leaching of bauxite with NaOH solution to obtain sodium aluminate solution. • The precipitation of pure aluminum hydroxide from this solution by seeding with fine crystals of Al(OH)3 . The leaching step was invented five years after the precipitation step (Table 1), and the precipitation step was an improveme...

Integrated temperature-humidity-sensitive thick-film structures based on spinel-type semiconducting ceramics of different chemical compositions and magnesium aluminate ceramics were prepared and studied. It is shown that temperature-sensitive thick-film structures possess good electrophysical characteristics in the region from 298 to 358 K. The change of electrical resistance in integrated thic...

It is noted that as a generalized characteristic of the functional gas generator, which sensitive to variations in its parameters, it advisable use transfer function, or analogue - amplitude-phase frequency generator. The generator includes two components amplitude-frequency and phase-frequency characteristics. During operation there will be parameters transmission coefficient time constants, d...

Abstract In the present study, high surface area boehmite nanopowder was recovered from aluminum cans waste. The sodium aluminate solution first prepared by dissolving in NaOH and then, H 2 O added to precipitate boehmite. characterized means of X-ray diffraction (XRD), transmission electron microscopy (TEM) N adsorption–desorption techniques. thermal stability sample investigated using thermog...

In this study, we reported a simple and easy process for zeolite synthesis using waste glass aluminum scraps. The silica source was obtained from of the end-of-life fluorescent tubes scraps collected workshop in region Sfax, Tunisia. zeolitic materials were prepared by hydrothermal treatment at 60 °C 6 days 10 g powder mixed with 100 mL sodium aluminate solution order to optimize nature recover...

Zeolites Na-A and Na-X are important synthetic zeolites widely used for separation and adsorption in industry. It is of great significance to develop energy-efficient routines that can synthesize zeolites Na-A and Na-X from low-cost raw materials. Coal fly ash (CFA) is the major residue from the combustion of coal and biomass containing more than 85% SiO2 and Al2O3, which can readily replace th...