A single-crystal to single-crystal (SC-SC) transformation process driven by water molecules has been exhibited by a multi-metallic coordination polymer. The in situ heating single crystal X-ray diffraction technique was applied to study the control of metal ion movement in the reversible SC-SC transformation process.

In this paper, we report on the synthesis of Cu nanoparticles through a single-precursor route by controlling the growth temperature. Selective adsorption of oleylamine on various crystal planes may play an important role in the growth process. The understanding of this self-assembling process will help us develop reliable and reproducible methods to synthesis other three dimensional nanostruct...

In this study, a feasible green method for the synthesis of copper oxide nanocrystalline is described by using sour cherry juice which has a significant effect on crystalline size, and morphology. The benefits of the green method, not only nanometer scale are formed but also low-cost method are obtained in a normal atmosphere which it has been used (CH3COO)2Cu.H2O individually as Cu sources. Al...

In this study, a feasible green method for the synthesis of copper oxide nanocrystalline is described by using sour cherry juice which has a significant effect on crystalline size, and morphology. The benefits of the green method, not only nanometer scale are formed but also low-cost method are obtained in a normal atmosphere which it has been used (CH3COO)2Cu.H2O individually as Cu sources. Al...

Two new nano-sized lead(II) and mercury(II) coordination polymers, [Pb(2-bpdh)(NO3)2(H2O)]n(1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza- 2,4-hexadiene)} and [Hg(4-bpdb)(SCN)2]n (2); (4-bpdb= 1,4-bis(4- pyridyl)-3,4-diaza-1,3-butadiene) were synthesized by a sonochemical method. The structure of 1 may be considered coordination polymer of lead(II) and Single crystal X–ray analysis of compound ...

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhed...

The temperature dependence of magneto-optical and magneto-photoconductivity measurements were carried out in the range of (200-330) K. A home made optical cryostat was used for the measurements. The measured room temperature value of the energy gap was found to be 2.211 eV. The temperature coefficient of energy gap was found to be -5.48×10-4 eV/K obtained by the optical absorption method and -4...