A flexible diastereoselective approach to trans-(3S)-hydroxyprolinol derivatives is described, which is based on the samarium diiodide-mediated reductive coupling of the chiral 1-pyrroline N-oxide (nitrone)(S)-10 with carbonyl compounds. The reductive hydroxyalkylation of nitrone 10 with ketones and aromatic aldehydes is highly diastereoselective in establishing the C-2 chiral center of the pyr...

Using the local subgroup strategy of [3] and [4], we classify the radical subgroups and chains of the Fischer simple group Fi22 and verify the Alperin weight conjecture and the Uno reductive conjecture for this group; the latter is a refinement of the Dade reductive and Isaacs-Navarro conjectures.

The unipotent groups are an important class of algebraic groups. We show that techniques used to compute with finitely generated nilpotent groups carry over to unipotent groups. We concentrate particularly on the maximal unipotent subgroup of a split reductive group and show how this improves computation in the reductive group itself.

Paracoccus pantotrophus cytochrome cd(1) nitrite reductase is isolated under aerobic conditions from anaerobically grown cells in an inactive form. This state requires reductive activation to make it catalytically competent for nitrite reduction. In this work, we discuss the methods of this reductive activation and its consequences for the cell.

We expand a partial difference equation (P∆E) on multiple lattices and obtain the P∆E which governs its far field behaviour. The perturbative–reductive approach is here performed on well known nonlinear P∆Es, both integrable and non integrable. We study the cases of the lattice modified Korteweg–de Vries (mKdV) equation, the Hietarinta equation, the lattice Volterra–Kac–Van Moerbeke (VKVM) equa...

Symmetrical bis-aryl platinum complexes (DPPF)Pt(C(6)H(4)-4-R)(2) (R = NMe(2), OMe, CH(3), H, Cl, CF(3)) and electronically unsymmetrical bis-aryl platinum complexes (DPPF)Pt(C(6)H(4)-4-R)(C(6)H(4)-4-X) (R = CH(3), X = NMe(2), OMe, H, Cl, F, CF(3); R = OMe, X = NMe(2), H, Cl, F, CF(3); R = CF(3), X = H, Cl, NMe(2); and R = NMe(2), X = H, Cl) were prepared, and the rates of reductive elimination...

Taylor, Dewey Terese. Fine Bruhat Intersections for Reductive Monoids. (Under the direction of Mohan S. Putcha.) Fine Bruhat intersections for reductive groups have been studied by several authors in connection with Kazhdan-Lusztig theory, canonical bases and Lie Theory. The purpose of this thesis is to study the analogous intersections for reductive monoids. We determine the conditions under w...

Selected PCB congeners (PCB 52, 77, and 153) singly and in mixtures were spiked and aged in soil microcosms and subsequently planted with switchgrass (Panicum virgatum) or poplar (Populus deltoids x nigra DN34). The planted reactors showed significantly greater reductions in PCB parent compounds when compared to unplanted systems after 32 weeks, both in single congener exposures and when all th...