Engineering problems frequently require solving a sequence of dual linear systems. This paper introduces recycling BiCG, that recycles the Krylov subspace from one pair of linear systems to the next pair. Augmented bi-Lanczos algorithm and modified two-term recurrence are developed for using the recycle space. Recycle space is built from the approximate invariant subspace corresponding to eigen...

An electrochemical cell coupled with a recycle loop through a transmission FTIR cell is employed in studies of two free radical organic reactions, the oxidation of allylic alcohols and the trifluoromethylation of heteroarenes. Rapid mixing through the recycle loop allows continuous monitoring of reaction progress. Electrochemical generation of free radicals allows their controlled mediation int...

The chemical process industry aims particularly at energy, capital expenditure and variable feedstock cost savings due to fierce global competition, the Kyoto Protocol and requirements for sustainable development. Increasingly conceptual process design methods are used in the industry to achieve these aims. They are used in: • existing processes to renew parts; • process re-designs based on exi...

Complex process plants increasingly appear in modern chemical industry due to the considerable economic efficiency that complex and interactive process designs can offer. Interactions between process units (e.g., material recycle and energy integration) often cause significant difficulties in plantwide control. As such, it is important to study plantwide operability (i.e., whether a plantwide p...

The structure of thermally coupled distillation systems offers several control challenges arising from the transfer of vapor (or liquid) streams between columns. In particular, the presence of recycle streams for coupled schemes has led to the notion that control problems might be expected during the operation of these systems, in contrast to the rather well-known behavior of conventional disti...

A new simulation model for Hydrogen production is developed on the Aspen Plus platform. Designing, Analysis and Optimization of the Metal Chloride based cyclic process is done thereby calculating the energy, exergy and overall efficiency of the same using the simulation software. Kinetic and thermodynamic analysis of chemical reactions occurring in each equipment of the proposed model is done. ...

Life cycle assessment (LCA) has been used widely to estimate the environmental implications of deploying algae-to-energy systems even though no full-scale facilities have yet to be built. Here, data from a pilot-scale facility using hydrothermal liquefaction (HTL) is used to estimate the life cycle profiles at full scale. Three scenarios (lab-, pilot-, and full-scale) were defined to understand...