نتایج جستجو برای: pyrroles
تعداد نتایج: 1881 فیلتر نتایج به سال:
Other than triarylamines, which are protonated by strong acids both at their N-atom and aromatic rings, pyrrole its N-substituted derivatives were exclusively the carbon atoms of heteroaromatic rings. Whereas with trifluoromethane sulfonic acid (TFS) stable pyrrolium salts obtained, weaker trifluoroacetic (TFA) oligomers formed. E.g., from N-(tert-butyl)pyrrole a dimeric compound could be unamb...
Conditions allowing the one pot 2,5-diheteroarylation of 2,5-dibromothiophene derivatives in the presence of palladium catalysts are reported. Using KOAc as the base, DMA as the solvent and only 0.5-2 mol % palladium catalysts, the target 2,5-diheteroarylated thiophenes were obtained in moderate to good yields and with a wide variety of heteroarenes such as thiazoles, thiophenes, furans, pyrrol...
The enantioselective vinylogous Michael reaction of vinylketene silyl N,O-acetals derived from α,β-unsaturated N-acyl pyrroles and a broad range of α,β-unsaturated aldehydes proceeds with good regio-, diastereo-, and enantioselectivity when the Hayashi-Jørgensen diphenylprolinolsilylether was employed as a chiral organocatalyst. Products were obtained in generally good yields and as single ster...
The structure of the title compound, C(16)H(19)N(3)O(4)S, shows the planes described by the thio-phene and the pyrroles are twisted by 17.06 (4)°. Additionally, the structure shows the azomethine bond adopts the E configuration, while the pyrrole is disordered as a heterocycle flip [occupancy ratio 0.729 (5):0.271 (5)]. The three-dimensional network is well packed and involves N-H⋯O hydrogen bo...
The Pd(TFA)2-catalyzed [4+1] annulation of chained or cyclic α-alkenyl-dicarbonyl compounds and unprotected primary amines for “one-pot” synthesis of pyrroles is reported here. Enamination and amino-alkene were involved in this practical and efficient tandem reaction. The annulation products were isolated in moderate to excellent yields with O2 as the terminal oxidant under mild conditions. In ...
A catalytic diastereoselective aldol reaction has been developed for N1-arylated/C2-O-silylated/C3-methylated and brominated/C4-O-methylated pyrroles in its reactions with various aldehydes. Syn adducts emerge with regard to the vicinal nitrogen and oxygen heteroatom substituents. The N1-aryl residue undergoes oxidative cleavage, and the C3-bromine atom undergoes palladium-mediated coupling rea...
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