Graptolite–argillites (black shales) are studied as potential source of different metals. In the processing technologies graptolite–argillites, a preceding thermal treatment is often applied. this study, behavior Estonian graptolite–argillite (GA) samples from Toolse, Sillamäe and Pakri areas were using Setaram Labsys Evo 1600 thermoanalyzer coupled with Pfeiffer OmniStar Mass Spectrometer. The...

Understanding the stability and reactivity of iron sulfide phases is key to developing predictive capabilities for assessing their corrosion and catalytic activity. The differences between the free surface and the bulk interior of such phases are of particular importance in this context. Here, we employ density functional theory to investigate the formation energetics and electronic structure o...

Water chemical analysis of 100 springs from the Orco and the Tinée valleys (Western Italy and Southern France) and a 7 year groundwater chemistry monitoring of the 5 main springs were performed. All these springs drain from crystalline rock slopes. Some of these drain from currently active gravitational slope deformations. All groundwaters flowing through presently unstable slopes show anomalie...

Bacterial adhesion to mineral surfaces plays an important role not only in bacterial survival in natural ecosystems, but also in mining industry applications. Selective adhesion was investigated with Thiobacillus ferrooxidans by using four minerals, pyrite, quartz, chalcopyrite, and galena. Escherichia coli was used as a control bacterium. Contact angles were used as indicators of hydrophobicit...

The adsorption of Mycobacterium Phlei cells on the surfaces of pyrite and sphalerite was studied as functions of time and pH. The results indicated that a higher amount of cells adsorbing onto pyrite compared with that onto sphalerite under neutral and alkaline conditions, and it was also observed from photographs of scanning electron micrograph. To gain a better insight into the mechanisms of ...

Extensive horizons of pyritic shale occur in Mid-Proterozoic sediments of the eastern Belt basin, Montana, U.S.A. These pyritic shales are of striped appearance. Laminated pyrite beds alternate with non-pyritic shale beds. Laminated pyrite beds have wavy-crinkly internal laminae and are interpreted as mineralized microbial mats. Pyrite is essentially the only sulfide mineral in these shales. Py...

Chemical and spectroscopic studies have shown that in agricultural soils most of the soil sulphur (>95%) is present as sulphate esters or as carbon-bonded sulphur (sulphonates or amino acid sulphur), rather than inorganic sulphate. Plant sulphur nutrition depends primarily on the uptake of inorganic sulphate. However, recent research has demonstrated that the sulphate ester and sulphonate-pools...

Tailings are a residual material stream produced in the mineral processing of ores. They may contain major sulphide content that increases risk acid rock drainage (ARD) but also host valuable metals. Tank bioleaching is technically viable method to treat tailings. However, significant pyrrhotite cause increased and oxidant consumption result longer retention times process. In this work, non-oxi...