Palladium-copper alloys continue to be of interest for hydrogen membrane applications because of their high catalytic activity for hydrogen dissociation, high hydrogen permeability, robustness, and degradation resistance in the presence of sulfur-containing compounds. This sulfur tolerance makes these alloys attractive for membrane applications where sulfur compounds are likely to be present, s...

For obtaining good joints by soldering, a wettability of liquid metal on the solid metal surface, relatlatte, relattlated o solderability, is one of the most important factors, and the wettability is accelerated by using a suitable flux and atmosphere. In atmosphere soldering the flow of molten solder will be retarded by oxide films on base metals formed by a small amount of oxygen in atmospher...

In the frame of the Italian TRASCO program, we have studied the possibility to stiff SC cavities by deposition of thermal sprayed copper on thin niobium. We have investigated the use of the Laser Flash technique to test the thermal conductivity in the normal direction of deposited copper with the Pure Coat technique. The use of Au-Fe/Cromel P thermocouples as temperature sensors, motivated by t...

The electrochemical and corrosion behaviour of Al-6061, Al-4.5%Cu and Al-7.5%Cu alloys were studied in 0.50 M KSCN solution at 25 C. Open-circuit potential, Tafel polarization and ICP-AES measurements were used to study the uniform corrosion process on the surfaces of the tested alloys. Cyclic polarization measurements were employed for pitting corrosion studies. Obtained results were compared ...

A glyoxysomal copper,zinc-containing superoxide dismutase (EC 1.15.1.1) was purified to homogeneity, for the first time, from watermelon cotyledons (Citrullus vulgaris Schrad.). The stepwise purification procedure consisted of acetone precipitation, batch anion-exchange chromatography, anion-exchange Fast Protein Liquid Chromatography and gel-filtration column chromatography. Pure copper,zinc-s...

Copper nanoparticle synthesis has been gaining attention due to its availability. However, factors such as agglomeration and rapid oxidation have made it a difficult research area. In the present work, pure copper nanoparticles were prepared in the presence of a chitosan stabilizer through chemical means. The purity of the nanoparticles was authenticated using different characterization techniq...

The remarkable activity displayed by copper(I)phosphinite complexes of general formula [CuBr(L)] in two challenging cycloadditions is reported: a) the one pot azidonation/cycloaddition from boronic acids, NaN3 and terminal alkynes; b) the cycloaddition of azides and iodoalkynes. These airstable catalysts led to very good results in both cases and the expected triazoles could be isolated pure un...

Cross-coupling reactions between lipophilic terminal alkynes and aryl bromides can be catalyzed by ligated Pd, in the absence of copper, in pure water at ambient temperatures. Small amounts of the nonionic amphiphile PTS assist by virtue of nanometer micelles formed spontaneously in an aqueous medium.

In the paper, the Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) results of the surface layer formed on pure titanium after plasma electrolytic oxidation (micro arc oxidation) at the voltage of 450 V are shown. As an electrolyte, the mixture of copper nitrate Cu(NO₃)₂ (10-600 g/L) in concentrated phosphoric acid H₃PO...

The epitaxial growth of graphene on catalytically active metallic surfaces via chemical vapor deposition (CVD) is known to be one of the most reliable routes toward high-quality large-area graphene. This CVD-grown graphene is generally coupled to its metallic support resulting in a modification of its intrinsic properties. Growth on oxides is a promising alternative that might lead to a decoupl...