The influence of two organic amendments on norflurazon sorption-desorption processes in four soils with very different physicochemical characteristics was studied in laboratory experiments to evaluate the potential leaching of this pesticide through organic fertilized soils. Sorption-desorption experiments were performed on original soils and on a mixture of these soils with urban waste compost...

Use of reclaimed wastewater for irrigation is an important route for the introduction of pharmaceutical compounds (PCs) into the environment. In this study, the mobility and sorption-desorption behavior of carbamazepine, naproxen and diclofenac were studied in soil layers sampled from a plot irrigated with secondary-treated wastewater (STWW). Carbamazepine and diclofenac were significantly reta...

The sorption efficiencies of graphene oxide (GO) and functionalized multi-walled carbon nanotubes (f-MWCNTs) were investigated and elucidated to study their potential in treating acid mine drainage (AMD) containing Cu2+, Mn2+, Zn2+, Pb2+, Fe3+ and Cd2+ metal ions. Several layered GO nanosheets and f-MWCNTs were formed via the modified Hummers’ method and the acid treatment of the MWCNTs, respec...

Human hair shavings were characterized as a sorbent for trace metals. At pH 7.0 metal sorption follows the order Pb(II)>Cd(II)>Cr(VI)>Fe(III)>Cu(II)>Ni(II)>Mn(VI). Metal recovery is quantitative for Pb and Cd after 30 min of equilibration. Recovery of other metals is less quantitative and varies with pH. For example, while Cu is best recovered at pH 5, Ni and Mn are sorbed optimally in the basi...

The influence of humic acid (HA) on Ni(II) sorption to Ca-montmorillonite was examined by using a combination of batch sorption experiments and extended X-ray absorption fine structure (EXAFS) spectroscopy technique. The sorption of Ni(II) on HA-montmorillonite hybrids is strongly dependent on pH and temperature. At low pH, the sorption of Ni(II) is mainly dominated by Ni-HA-montmorillonite and...

The characteristics and mechanisms of Pb sorption by biochars produced from sugarcane bagasse at 250, 400, 500, and 600 °C were examined. The Pb sorption isotherms, kinetics and desorption were investigated. All biochars were effective in Pb sorption and were well described by Langmuir isotherm model and pseudo-second-order kinetic model. The maximum sorption capacity decreased from 21 to 6.1 m...

X-ray absorption spectroscopy (XAS) studies revealed that Ni(II), Co(II), and Zn(II) formed LDH preFormation of surface-induced precipitates may play an important cipitates on Al-bearing minerals and in soil at pH $ 7 role in the immobilization of Ni and other metals in nonacidic soils. (d’Espinose de la Caillerie et al., 1995; Towle et al., To investigate the influence of commonly present orga...

M31 are divalent and trivalent metal cations, respectively, and A is an interlayer anion that may include The formation of Ni surface precipitates on natural soil materials NO3, silicate, or water] in which the metals are aligned may occur during sorption under ambient environmental conditions. in brucite-like octahedral sheets with anions in the interIn this study, we examined protonand ligand...

In this study, batch sorption and desorption experiments were conducted for testosterone using four agricultural soils and five clay minerals. Significant differences in sorption behavior were observed between abiotic and biotic systems. The Freundlich sorption coefficient Kf ðμg=gÞ=ðμg=mLÞn ranged from 8.53 to 74.46 for soils and from 35.28 to 1,243 for clays. The maximum sorption capacity (μg...

the relationship between some measure of soil P and runoff dissolved P (Gburek et al., 2000; Coale et al., The relationship between soil test P (STP) and dissolved reactive 2002; Vadas et al., 2002). However, recent research has P (DRP) in runoff has been shown to vary with soil type due to differences in soil properties. This study was conducted to determine shown that this relationship will v...