A strong–metal support interaction construction was induced via ultrasonication in water as described by Zhenzhen Yang, Sheng Dai et al. their Communication (e202214322). The encapsulation degree of metal nanoparticles reducible oxide overlayers can be modulated the parameters. facile tunability offers enhanced activity and selectivity diverse catalytic hydrogenation applications. cover picture...

Polyoxometalates (POMs) have been a popular motif in crystal engineering. In this work, seven ionic crystals based on Keggin- or Dawson-type POMs and mononuclear Bi(III) complexes were synthesized. The center exhibited triangular dodecahedron, square antiprism, pseudo-cubic eight-coordination geometries, with DMSO DMF as ligands. showed polymorphic transformations, high proton conductivities de...

Polyoxometalates (POMs) are transition metal oxygen anionic clusters that oxidatively and thermally robust due to their inorganic, oxide-like nature. The versatility of structures compositions ensures tunable acid redox properties, solubility, functionality. potential POMs as homogeneous catalysts building blocks for the construction heterogeneous selective oxidations is being intensively inves...