Polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) and polybrominated diphenyl ethers (PBDEs) were characterized and quantified in stack gas from secondary ventilation systems from five different steelmaking plants. The concentrations of 2,3,7,8-substituted PBDD/Fs (2,3,7,8-PBDD/Fs) and PBDEs were 0.036–0.19 ng/Nm (0.32–4.33 pg toxic equivalency (TEQ)/Nm) and 3.11–40.0 ng/Nm, respecti...