A central issue in material science is to obtain understanding of the electronic correlations that control complex materials. Such electronic correlations frequently arise because of the competition of localized and itinerant electronic degrees of freedom. Although the respective limits of well-localized or entirely itinerant ground states are well understood, the intermediate regime that contr...

Uranium and plutonium's 5f electrons are tenuously poised between strongly bonding with ligand spd-states and residing close to the nucleus. The unusual properties of these elements and their compounds (e.g., the six different allotropes of elemental plutonium) are widely believed to depend on the related attributes of f-orbital occupancy and delocalization for which a quantitative measure is l...

Previous Advanced Fuel Cycle Initiative (AFCI) studies were made to assess the effects of the existing accumulation of LWR spent fuel in the United States on the capability to partition/transmute actinides using existing and advanced LWRs. The concept of treating the “oldest fuel first” indicated that significant advantages could be gained in both partitioning, transmutation, and in overall cos...

The Fixed-Energy Response-Function Analysis with Multiple Efficiency (FRAM) code was developed at Los Alamos National Laboratory to measure the gamma-ray spectrometry of the isotopic composition of plutonium, uranium, and other actinides. We have studied and identified two different kinds of errors from FRAM analysis: random and systematic. The random errors come mainly from statistics and are ...

Internal exposure from naturally occurring radionuclides (including the inhaled long-lived actinides (232)Th and (238)U) is a component of the ubiquitous background radiation dose (National Council on Radiation Protection and Measurements. Ionizing radiation exposure of the population of the United States; NCRP Report No. 160; NCRP: Bethesda, MD, 2009). It is of interest to compare the concentr...

Introduction: Angrites are igneous meteorites that crystallized very early in the solar system, ~10 Ma after CAIs, as also implied by the presence of now extinct short-lived radionuclides such as Mn, Sm and Pu [1]. Fission Xe was used to calculate Pu-Xeretention ages of eucrites, relative to that of Angra dos Reis (AdoR) [2]. AdoR has an absolute Pb-Pb age of 4557.8 Ma [see 1 for ref.]. Most eu...

A non-destructive, gamma-spectrometric method for verifying the plutonium content of Pu-Be neutron sources has been developed. It is also shown that the isotopic composition and the age of plutonium (Pu) can be determined in the intensive neutron field of these sources by the “Multi-Group Analysis” method. Gamma spectra were taken in the far-field of the sample, which was assumed to be cylindri...

Grab samples of sediment were collected at 530 locations in Lake Michigan, primarily in the southeastern quarter of the lake. Each sample was analysed in the field and in the laboratory for fallout cesium-137. Twenty-five of the samples, collected near the mouth of the St Joseph River, were also analysed in the laboratory for 11 other man-made materials known to be discharged into the river. Tw...

The most relevant species of plutonium tricarbide were characterized using theoretical methods. The global minimum is predicted to be a fan structure where the plutonium atom is bonded to a quasi-linear C3 unit. A rhombic isomer, shown to be a bicyclic species with transannular C-C bonding, lies about 39 kJ/mol above the fan isomer. A linear PuCCC isomer and a three-membered ring CPuC2 isomer w...