نتایج جستجو برای: platinum metal compounds

تعداد نتایج: 431810  

2005
C W Corti

When a metallic powder is subjected to a suffkiently high pressure a certain amount of adhesion takes place between individual particles. If this compact i s then sintered the bond is improved by diflusion and intergranular grain growth. The earliest known platinum objects were fabricated by such a powder metallurgical process, and when European scientists first addressed the problem of manufac...

Journal: :Chemistry 2016
Masaki Yoshida Naoki Yashiro Hotaka Shitama Atsushi Kobayashi Masako Kato

A redox series of cyclometalated platinum complexes based on a dinuclear motif linked by acetamidato (aam) bridging ligands, [Pt2 (μ-aam)2 (ppy)2 ] (ppy(-) =2-phenylpyridinate ion), has been synthesized. The complexes in this series are easily oxidized and reduced by both electrochemical and chemical methods, and this is accompanied by multistep changes in their optical properties, that is, mul...

2012
J J Eksteen E. Schoeman

Ion exchange resins were investigated for the effective recovery of platinum, palladium, and gold from a pregnant cyanide heap leach solution. Screening results indicated that strong-base anion exchange resins proved to be most effective in the recovery of these metal cyanides. Gold was selectively recovered with the use of Minix, while effective recovery of gold, platinum, and palladium over t...

Journal: :Proceedings of the National Academy of Sciences of the United States of America 2013
Sammual Yu-Lut Leung Wai Han Lam Vivian Wing-Wah Yam

Platinum(II)-containing complexes with inherently chiral binaphthol derivatives display a versatile scaffold between random coils and single-turn helical strands, in which the conformational transition is controlled by the Pt···Pt and π-π interactions of alkynylplatinum(II) terpyridine moiety upon solvent and temperature modulation. The bisignate Cotton effect in the circular dichroism spectra ...

2016
Rajesh Kumar Jyothi Jin-Young Lee

Macrocyclic compounds (crown ethers), specifically 18-crown-6 (18-C-6), benzo-15-crown-5 (B-15-C-5), di-benzo-18-crown-6 (DB-18-C-6) and di-cyclohexano-18-crown-6 (DC-18C-6), are used as extractants as well as synergists with amine-group extractants. Platinum and rhodium belong to platinum-group metals (PGMs) and have very similar ionic radii and similar properties. The separation of PGMs is mo...

Journal: :Science 2011
Gang Wu Karren L More Christina M Johnston Piotr Zelenay

The prohibitive cost of platinum for catalyzing the cathodic oxygen reduction reaction (ORR) has hampered the widespread use of polymer electrolyte fuel cells. We describe a family of non-precious metal catalysts that approach the performance of platinum-based systems at a cost sustainable for high-power fuel cell applications, possibly including automotive power. The approach uses polyaniline ...

Journal: :European Journal of Inorganic Chemistry 2009

Journal: :Cancer research 1986
S K Mauldin I Husain A Sancar S G Chaney

Previous studies have investigated the cytotoxicity of platinum(II) compounds with bidentate leaving ligands, but little is known about their uptake or mechanism of action inside the cell. We have compared the uptake and intracellular effects of cis-1,2-diaminocyclohexanemalonatoplatinum(II) [Pt(mal)(cis-DACH)] and cis-1,2-diaminocyclohexanedichloroplatinum(II) [PtCl2(cis-DACH)] in the L1210 ce...

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