X-Ray crystal structures are reported for five silver(I) complexes of four monoterpenoid alkenes. Discrete mononuclear complexes of the chiral alkenes (1S)-(-)-α-pinene and (1S)(-)-β-pinene with silver perchlorate and silver hexafluorophosphate are described. The achiral diene γ-terpinene forms a discrete mononuclear adduct with silver hexafluorophosphate and a two-dimensional polymeric network...

Juniperus communis is a shrub or small evergreen tree, native to Europe, South Asia, and North America, and belongs to family Cupressaceae. It has been widely used as herbal medicine from ancient time. Traditionally the plant is being potentially used as antidiarrhoeal, anti-inflammatory, astringent, and antiseptic and in the treatment of various abdominal disorders. The main chemical constitue...

Sampling of monoterpenes from air on the Tenax porous polymer may introduce analytical errors owing to oxidation and acid rearrangements on the adsorbent. Particularly terpenes which react rapidly with ozone, e.g. myrcene and limonene, are partially lost when sampling air with high photooxidant levels. On acidified adsorption cartridges, a-pinene and ~-pinene may be converted to camphene, limon...

Monoterpenes, emitted in large quantities by trees to attract pollinators and repel herbivores, can exist in mirror image forms called enantiomers. In this study such enantiomeric pairs have been measured in ambient air over extensive forest ecosystems in South America and northern Europe. For the dominant monoterpene, α-pinene, the (−)form was measured in large excess over the (+)-form over th...

The essential oil from the dried leaves of Chromolaena odorata (L.) R.M. King & H. Rob. was obtained by hydrodistillation and analyzed by gas chromatography-mass spectrometry (GC-MS). The major components were α-pinene (42.2%), β-pinene (10.6%), germacrene D (9.7%), β-copaen-4α-ol (9.4%), (E)caryophyllene (5.4%), and geijerene/pregeijerene (7.5%). The oil was screened for antimicrobial activity...

Abstract. A comprehensive chamber investigation of photochemical secondary organic aerosol (SOA) formation and transformation in mixtures anthropogenic (o-cresol) biogenic (α-pinene isoprene) volatile compound (VOC) precursors the presence NOx inorganic seed particles was conducted. To enable direct comparison across systems, initial concentration (hence reactivity) systems towards dominant OH ...

The Douglas fir terpene alpha-pinene was shown to inhibit the growth of a variety of bacteria and a yeast. Other terpenes of the Douglas fir, including limonene, camphene, and isobornyl acetate, were also inhibitory to Bacillus thuringiensis. All terpenes were inhibitory at concentrations normally present in the fir needle diet of Douglas fir tussock moth larvae. The presence of such terpenes i...

The essential oils of the flowers, leaves and stems of Senecio polyanthemoides Sch. Bip. Samples collected from two different localities within the city of uMhlathuze, KwaZulu-Natal Province (South Africa) were isolated by hydrodistillation and analyzed using GC and GC/MS. Twenty-six constituents were identified, representing an average of 86.0 - 99.6% of the total oil composition. The chemical...

The essential oil composition of Rhus cotinus L. (syn. Cotinus coggygria Scop.; Family: Anacardiaceae), was analyzed by GC and GC-MS. The in vitro antioxidant activity was assessed by β-carotene bleaching test, reducing power, DPPH radical scavenging and inhibition of lipid peroxidation methods. A total of 30 compounds were identified with the dominance of monoterpenes (65.9%) viz. β-Pinene, ca...

Pinenes and pinene dimers have similar energy densities to petroleum-based fuels are regarded as alternative fuels. The pyrolysis of the pinenes is well studied, but information on their combustion kinetics limited. Three stoichiometric, flat premixed flames C10H16 monoterpenes ?-pinene, ?-pinene, myrcene were investigated by synchrotron-based photoionization molecular-beam mass spectrometry (P...