A flow injection (FI) system was used to develop an efficient on-line sorbent extraction preconcentration system for palladium by graphite furnace atomic absorption spectrometry (GFAAS). The investigated metal was preconcentrated on a microcolumn packed with 1,5-bis(di-2-pyridyl)methylene thiocarbohydrazide immobilized on silica gel (DPTH-gel). The palladium is eluted with 40mul of HCl 4M and d...

The reaction between palladium acetate and IMES.HCl leads to the formation of a novel palladium complex. The X-ray crystal structure analysis reveals that the palladium is C(2) bound to one NHC ligand (the normal binding mode), whereas the second ligand is attached through the C(5) carbon of the second imidazolium. The metalation site on the imidazolium salt is strongly influenced by the presen...

Herein the modifications of a glassy carbon electrode (GCE) with palladium nanoparticles and a palladium film are reported. The response to hydrogen peroxide on the modified electrode was examined using cyclic voltammetry and amperometry (at –0.2 V vs. Ag/AgCl reference electrode in the phosphate buffer solution, pH 7.4). The palladium film and palladium nanoparticle-modified GCE showed a linea...

In this paper, we present the results of single-electron tunneling in two-dimensional (2D) hexagonal closed packed arrays of palladium nanoparticles. After inspecting the emergence of Coulomb blockade phenomena, we demonstrate the possibilities of using these arrays as a single-electron tunneling based hydrogen sensor. We assumed arrays of palladium nanoparticles with diameters of 3.5 and 6...

We explore electro-catalytic properties of a system consisting of platinum and palladium nanoparticles dispersed over a nanotubular self-organized TiO2 matrix. These electrodes prepared by electroess and microemulsion of palladium and palladium nanoparticles on to TiO2 nanotubes, respectively. Titanium oxide nanotubes were fabricated by anodizing titanium foil in ethylene glycol (EG) fluoride-c...

Today, development of resistance to anticancer drugs (including cisplatin) is noticed as a major problem. Recently several studies demonstrated that palladium complexes showed remarkable cytotoxic effects against K562 cell line and could be used efficiently for treatment of many human cancers including leukemia. Hereof, K562 cells were made resistant to cisplatin using increasing concentration ...

Pancreatic carcinoma ranks among the most lethal of human cancers. Besides late detection, other factors contribute to its lethality, including a high degree of chemoresistance, invasion, and distant metastases. Currently, the mainstay of therapy involves resection of local disease in a minority of patients (Whipple procedure) and systemic gemcitabine. While systemic chemotherapy has some benef...

Occupational asthma caused by palladium. M. Daenen, Ph. Rogiers, C. Van de Walle, F. Rochette, M. Demedts, B. Nemery. #ERS Journals Ltd 1999. ABSTRACT: Occupational exposure to complex platinum salts is a well-known cause of occupational asthma. Although there is evidence that platinum refinery workers may also be sensitized to other precious metals, such as palladium or rhodium, no instances o...

A simple and rapid liquid-liquid extraction of palladium has been studied involving ion-pairing of bromocomplexes of palladium(II) with hexadecylpyridinium bromide (HDPB) dissolved in chloroform. The stoichiometry and distribution of (HDP)2PdBr4 between the aqueous and organic phase was investigated by spectrophotometric mole ratio method. The extraction efficiency of palladium(II) by HDPB was ...