نتایج جستجو برای: oscillatory reaction

تعداد نتایج: 431746  

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه شهید بهشتی - دانشکده علوم 1371

we describe here a suitable approach for the synthesis of n-unsubstituted monocyclic b-lactams under mild reaction conditions by the annelation of imines with substituted acetylchlorides. in this method the reaily available phtalimidoacetyl chloride were allowed to react with - dibenzylideneiminotoluene (hydrobenzamide) in the presence of an equimolar amount of triethylamine in refluxing toluen...

Enhancement of heat and mass transfer and decrease of energy dissipation are great necessities of the evolution of fluid flow devices. Utilizing oscillatory or pulsatile fluid flow for periodic disturbing of velocity and thermal boundary layers is one of the methods with exciting results. Passive methods of generating oscillatory flow are preferred to active methods because of simplicity, no ne...

Journal: :Physical review. E, Statistical, nonlinear, and soft matter physics 2012
Tamás Bánsági Vladimir K Vanag Irving R Epstein

We observe standing waves of chemical concentration in thin layers [quasi-two-dimensional (2D)] and capillaries [three-dimensional (3D)] containing the aqueous Belousov-Zhabotinsky reaction in a reverse microemulsion stabilized by the ionic surfactant sodium bis-2-ethylhexyl sulfosuccinate (AOT) and with cyclo-octane as the continuous phase. The 3D structures are oscillatory lamellae or square-...

2001
Jichang Wang

In this study, we report the observation of oscillatory clusters in the photosensitive Belousov–Zhabotinsky reaction switching between excitable and unexcitable states. Numerical studies with a three-variable Oregonator model have been carried out in oneand two-dimensional media. Both non-flux and periodic boundaries have been characterized. Twoand three-phase clusters with standing, breathing,...

2015
Wei Zou D. V. Senthilkumar Raphael Nagao István Z. Kiss Yang Tang Aneta Koseska Jinqiao Duan Jürgen Kurths

Oscillatory behaviour is essential for proper functioning of various physical and biological processes. However, diffusive coupling is capable of suppressing intrinsic oscillations due to the manifestation of the phenomena of amplitude and oscillation deaths. Here we present a scheme to revoke these quenching states in diffusively coupled dynamical networks, and demonstrate the approach in expe...

Journal: :Physical review. E, Statistical, nonlinear, and soft matter physics 2001
R Gallego D Walgraef M S Miguel R Toral

The effect of a temporal modulation at three times the critical frequency on a Hopf bifurcation is studied in the framework of amplitude equations. We consider a complex Ginzburg-Landau equation with an extra quadratic term, resulting from the strong coupling between the external field and the unstable modes. We show that, by increasing the intensity of the forcing, one passes from an oscillato...

Journal: :I. J. Bifurcation and Chaos 2000
Andrei Goryachev Raymond Kapral Hugues Chaté

Spatially distributed reaction–diffusion media where the local dynamics exhibits complex oscillatory or chaotic dynamics are investigated. Spiral waves in such complex-oscillatory or excitable media contain synchronization defect lines which separate domains of different oscillation phases and across which the phase changes by multiples of 2π. Such synchronization defect lines arise from the ne...

2009
Jeremy Bellay Arnd Scheel

We investigate reaction-diffusion systems near parameter values that mark the transition from an excitable to an oscillatory medium. We analyze existence and stability of traveling waves near a steep pulse that arises as the limit of excitation pulses when parameters cross into the oscillatory regime. Traveling waves near this limiting profile are obtained by analyzing a codimension-two homocli...

2013
George E. Bass James E. Chenevey

The study reported here concerns a phenomenon, discovered and extensively investigated by Sorin Comorosan, wherein enzyme initial reaction rates are enhanced as a consequence of incorporation of solutions derived from previously irradiated crystalline material into the reaction medium. Effective irradiation times conform to a sharply oscillatory pattern. In most reports, the irradiated crystall...

Journal: :Computers & Chemical Engineering 2008
Zeljko Cupic Davor Loncarevic Ana Ivanovic Predrag Bankovic Srdan Petrovic

Identification of trends and their correspondence with dynamical state transitions are briefly discussed on several reaction network models. The nfluence of different threshold values on the trend analysis and dynamical state analysis results is examined. Both methods are applied here to he results of the numerical simulation. For this purpose the models of three reaction systems are used: simp...

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