Spectroscopic and kinetic studies indicate that oxo-carboxylato-molybdenum(VI) bis-dithiolene complexes, (Mo(VI)O(p-X-OBz)L2), have been generated at low temperature as active site structural models for the type II class of pyranopterin molybdenum DMSOR family enzymes. A DFT analysis of low energy charge transfer bands shows that these complexes possess a Mo-S(dithiolene) π-bonding interaction ...

We take a dynamical-systems approach to study the qualitative dynamical aspects of the tidal locking of the rotation of secondary celestial bodies with their orbital motion around the primary. We introduce a minimal model including the essential features of gravitationally induced elastic deformation and tidal dissipation that demonstrates the details of the energy transfer between the orbital ...

The ground state of NaxCoO2 (0.00.6 due to a_{1g} van Hove singularity near the band to...

We report on a timing analysis performed on a 62-ks long XMM-Newton observation of the accreting millisecond pulsar SAX J1808.4–3658 during the latest X-ray outburst which started on September 21st 2008. By connecting the time of arrivals of the pulses observed during the XMM-Newton observation we derived the best fit orbital solution and a best fit value of the spin period for the 2008 outburs...

We report on the chemical adsorption mechanism of atomic oxygen on the Pt(111) surface using angle-resolved-photoemission spectroscopy (ARPES) and density functional calculations. The detailed band structure of Pt(111) from ARPES reveals that most of the bands near the Fermi level are surface-states. By comparing band maps of Pt and O/Pt, we identify that dxz (dyz) and dz(2) orbitals are strong...

Optical properties of polar push–pull chromophore (diphenylpolyene with donor/acceptor terminal substituents) are studied using hybrid time-dependent density functional theory (TD-DFT). The optical transitions are thoroughly examined. This includes oneand two-photon absorption, and fluorescence, as a function of the underlying density functional, the basis set choice, and the solvent. Calculate...

We demonstrate the coherent transfer of the orbital angular momentum of a photon to an atom in quantized units of variant Planck's over 2pi, using a 2-photon stimulated Raman process with Laguerre-Gaussian beams to generate an atomic vortex state in a Bose-Einstein condensate of sodium atoms. We show that the process is coherent by creating superpositions of different vortex states, where the r...

Plasmonic vortices (PV) excited by a highly focused radially polarized optical vortex (RPOV) beam on a metal surface are investigated experimentally and theoretically. The proposed method reveals a direct phase singularity and orbital angular momentum (OAM) transfer from an incident structured beam to its counterpart in surface plasmon with dynamic, reconfigurable and high-efficiency advantages...

WZ Sge-type dwarf novae are characterized by long recurrence times of outbursts ( 10 yr) and short orbital periods (. 85 min). A significant part of WZ Sge stars may remain undiscovered because of low outburst activity. Recently, the observed orbital period distribution of cataclysmic variables (CVs) has changed partly because outbursts of new WZ Sge stars have been discovered routinely. Hence,...

Beams of hyperthermal K atoms cross beams of the oriented haloforms CF(3)H, CCl(3)H, and CBr(3)H, and transfer of an electron mainly produces K(+) and the X(-) halide ion which are detected in coincidence. As expected, the steric asymmetry of CCl(3)H and CBr(3)H is very small and the halogen end is more reactive. However, even though there are three potentially reactive centers on each molecule...