Combining the reduced hierarchy equations of motion (HEOM) approach with the Wigner-function formalism, we investigate nonperturbatively exciton dissociation under the influence of a phonon bath in an organic heterojunction. The exciton is modeled by an electron-hole pair with the electron moving in the presence of both an external electric field and the Coulomb attraction potential from the ho...

We study the surface tension of ionic solutions at air/water and oil/water interfaces by using field-theoretical methods and including a finite proximal surface-region with ionic-specific interactions. The free energy is expanded to first-order in a loop expansion beyond the mean-field result. We calculate the excess surface tension and obtain analytical predictions that reunite the Onsager-Sam...

We employ a generalized van der Waals-Onsager perturbation theory to construct a free energy functional capable of describing the thermodynamic properties and orientational order of the isotropic and nematic phases of attractive disc particles. The model mesogen is a hard (purely repulsive) cylindrical disc particle decorated with an anisotropic square-well attractive potential placed at the ce...

We study the relaxation dynamics of an isolated zero temperature quasi-two-dimensional superfluid Bose-Einstein condensate that is imprinted with a spatially random distribution of quantum vortices. Following a period of vortex annihilation the remaining vortices self-organize into two macroscopic coherent "Onsager vortex" clusters that are stable indefinitely--despite the absence of driving or...

Abstract. When taking the model error into account in data assimilation, one needs to evaluate the prior distribution represented by the Onsager–Machlup functional. Through numerical experiments, this study clarifies how the prior distribution should be incorporated into cost functions for discrete-time estimation problems. Consistent with previous theoretical studies, the divergence of the dri...

Inspired by the observations of a remarkably stable biaxial nematic phase [van den Pol et al., Phys. Rev. Lett. 103, 258301 (2009)], we investigate the effect of size polydispersity on the phase behavior of a suspension of boardlike particles. By means of Onsager theory within the restricted orientation (Zwanzig) model we show that polydispersity induces a novel topology in the phase diagram, w...