Abstract In the present study solution and coordination chemistry of copper(II)–alkyl- N -iminodiacetate systems are studied in aqueous by potentiometry, using ion selective copper pH electrodes, EXAFS (extended X-ray absorption fine structure) dye probe molecular spectrophotometry. Alkyl- -iminodiacetates with varying alkyl chain length, methyl (CH 3 –), n -hexyl (C 6 H 13 -dodecyl 12 25 –) -o...

many phragmites-dominated wetlands have been markedly salinized and alkalinized in the songnen plain, northeastern china. agricultural wastewater with high nitrogen content has been discharged into these alkalinized-salinized wetlands. to understand the effect of salinity-alkalinity on reed (phragmites australis) seedlings at various nitrogen levels, we examined photosynthesis rate, chlorophyll...

ABSTRACT. A novel distorted square-planar palladium(II) complex of the type [Pd(Hdz)(PPh3)Cl], where (Hdz = dithizone mono deprotonate and PPh3 triphenylphosphine), was synthesized in dichloromethane reactions between PdCl2 a mixture Hdz PPh3. The new Pd(II) has been identified by FT-IR, electronic spectra, DFT calculations, molar conductivity, single-crystal X-ray diffraction. An diffraction s...

To suppress the over-oxidation of solvents, reaction conditions were optimized, and ligands added to system facilitate oxidation sulfur compounds with molecular oxygen. The addition suitable nitrogen led effective suppression, 2,2′-bipyridine showed best performance among analyzed samples. After use ligand, yields by-products from solvent reduced by a factor 15 compared those without any ligands.

A wide range of research activities have been carried out so far on benzimidazole and pyridine derivatives to evaluate their Antiviral, Anticancer, Anticonvulsant, Anthelmintic Activity and many promising results are obtained with respect to the anticancer activity. Out of the various ligands used, the alkylating agents are found to be highly active with respect to cancer chemotherapy. Nitrogen...

The visible spectrum of a ligand-bound cytochrome P450 is often used to determine the nature of the interaction between the ligand and the P450. One particularly characteristic form of spectra arises from the coordination of nitrogen-containing ligands to the P450 heme iron. These type II ligands tend to be inhibitors because they stabilize the low reduction potential P450 and prevent oxygen bi...

Four novel complexes [Co(H2O)4(sul)2] 1, [Co(2-ampy)2(sul)2] 2, [Co(H2O)2(1,10-phen) (sul)2] 3 and [Co(2,9-dimephen)(sul)2] 4 (sul = sulindac, 2-ampy = 2-amino pyridine, 1,10-phen = 1,10-phenanthroline and 2,9-dimeph = 2,9-dimethyl-1,10-phenanthroline) were prepared and characterized by IR, UV-Visible spectroscopy and magnetic properties. The crystal structures of complexes 1 and 4 were determi...

The interactions between platinum complexes and human serum albumin (HSA) play crucial roles in the distribution, metabolism, and activity of platinum-based anticancer drugs. Octahedral platinum (IV) complexes represent a significant class of anticancer agents that display molecular pharmacological properties different from cisplatin. In this study, the interaction between two Pt(IV) complexes ...

Three bidentate Schiff bases having nitrogen and sulphur donor sequences were prepared by condensing S-benzyldithiocarbazate (NH(2)NHCS(2)CH(2)C(6)H(5)) with heterocyclic aldehydes. The reaction of diphenyltin dichloride with Schiff bases leads to the formation of a new series of organotin(IV) complexes. An attempt has been made to prove their structures on the basis of elemental analyses, cond...